| 153255-45-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 153255-45-9
• 化学式: C₂₀H₂₄BN
• 分子量: 289.228
• InChiKey: LABGLXZVKYSXTO-HDICACEKSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.92
• 重原子数：
  22.0
• 可旋转键数：
  3.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  3.24
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为产物：
  描述：

  二苯胺 、 9-borabicyclo[3.3.1]nonane dimer 在 Cp*Ti{MeC(NⁱPr)₂}(NBC₈H₁₄₎ 作用下， 生成
  参考文献：
  名称：

  Reactions of Titanium Hydrazides with Silanes and Boranes: N–N Bond Cleavage and N Atom Functionalization

  摘要：

  Reaction of Ti((N2N)-N-iPr)(NNPh2)(py) with Ph(R)SiH2 (R = H, Ph) or 9-BBN gave reductive cleavage of the N-alpha-Ni-beta bond and formation of new silyl- or boryl-amido ligands. The corresponding reactions of Cp*Ti-{MeC((NPr)-Pr-i)(2)}(NNR2) (R = Me or Ph) with HBPin or 9-BBN gave borylhydrazido-hydride or borylimido products, respectively. N-alpha and N-beta atom transfer and dehydrogenative coupling reactions are also reported.

  DOI：

  10.1021/jacs.5b06627

文献信息

• Alkaline‐Earth‐Catalyzed Dehydrocoupling of Amines and Boranes
  作者：David J. Liptrot、Michael S. Hill、Mary F. Mahon、Andrew S. S. Wilson

  DOI：10.1002/anie.201505949

  日期：2015.11.2

  Dehydrocoupling reactions between the boranes HBpin and 9‐borabicyclo[3.3.1]nonane and a range of amines and anilines ensue under very mild reaction conditions in the presence of a simple β‐diketiminato magnesium n‐butyl precatalyst. The facility of the reactions is suggested to be a function of the Lewis acidity of the borane substrate, and is dictated by resultant pre‐equilibria between, and the

  硼烷HBpin和9-borabicyclo [3.3.1]壬烷与一系列胺和苯胺之间的脱氢偶联反应在非常温和的反应条件下，在简单的β-二酮亚胺基化镁正丁基镁预催化剂的存在下发生。有人认为反应的便利性是硼烷底物的路易斯酸度的函数，并由催化过程中氢化镁和硼氢化物中间体之间的预平衡和相对稳定性决定。
• Reactions of β-Diketiminate-Stabilized Calcium Amides with 9-Borabicyclo[3.3.1]nonane (9-BBN)
  作者：Anthony G. M. Barrett、Mark R. Crimmin、Michael S. Hill、Peter B. Hitchcock、Panayiotis A. Procopiou

  DOI：10.1021/om070083t

  日期：2007.7.30

  The reaction of a β-diketiminate-stabilized calcium diphenylamide with the dialkylborane 9-BBN allows the synthesis of a β-diketiminate-stabilized calcium borohydride along with an amidoborane reaction coproduct via a likely σ-bond metathesis mechanism.

  β-二酮稳定的二苯基酰胺钙与二烷基硼烷9-BBN的反应可以通过可能的σ键易位机理合成β-二酮稳定的硼氢化钙以及酰胺基硼烷反应副产物。