(5,10,15-tri(p-dodecanoxyphenyl)-20-(p-hydroxyphenyl) porphyrin-2H)cobalt(II) | 1071815-09-2

• 分子结构分类: 有机化合物
• 英文名称: (5,10,15-tri(p-dodecanoxyphenyl)-20-(p-hydroxyphenyl) porphyrin-2H)cobalt(II)
• CAS: 1071815-09-2
• 化学式: C₈₀H₁₀₀CoN₄O₄
• 分子量: 1240.69
• InChiKey: OARHJZWTRVDAJH-LPVWYINYSA-N

反应信息

• 作为产物：
  描述：

  cobalt(II) diacetate tetrahydrate 、 5-(p-hydroxyphenyl)-10,15,20-tris(p-dodecoxyphenyl)porphyrin 以 吡啶 为溶剂， 生成 (5,10,15-tri(p-dodecanoxyphenyl)-20-(p-hydroxyphenyl) porphyrin-2H)cobalt(II)
  参考文献：
  名称：

  NO2 sensing ability of a monolayer of cobalt(II) porphyrin molecules covalently assembled on a engineered silica substrate

  摘要：

  The 5,10,15-tri-(p-dodecanoxyphenyl)-20-(p-hydroxyphenyl)- and 5,10,15,20-tetrakis-(p-dodecanoxyphenyl)cobalt porphyrin complexes were synthesized, purified and characterized. Silica substrates were functionalized with a covalent 4-ClCH(2)C(6)H(4)SiCl(3) monolayer. Additional covalent bonding of the 5,10,15-tri-(p-dodecanoxyphenyl)-20-(p-hydroxyphenyl)-cobalt porphyrin to the silylated substrates was further achieved. The monolayer surface chemical characterization was carried out by X-ray photoelectron measurements. Both the Co 2p and N 1s spectra are evident. The NO(2) sensing capability of the present cobalt porphyrin systems, at ppm levels, has been demonstrated. (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2008.02.055