SnCl4 * 2 triphenylphosphine | 17668-11-0

• 英文名称: SnCl4 * 2 triphenylphosphine
• CAS: 17668-11-0；23110-60-3；100896-37-5
• 化学式: C₃₆H₃₀Cl₄P₂Sn
• 分子量: 785.104
• InChiKey: VHLDJUDWYYGMTJ-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  SnCl4 * 2 triphenylphosphine 以 二氯甲烷 为溶剂， 生成 chlorotriphenylphosphonium trichlorostannate(II)
  参考文献：
  名称：

  Muratova, A. A.; Sobanova, O. B.; Yarkova, E. G., Journal of general chemistry of the USSR, 1980, vol. 50, p. 579 - 584

  摘要：

  DOI：
• 作为产物：
  描述：

  四氯化锡 在 triphenyl phosphine 作用下， 以 二氯甲烷 为溶剂， 以58%的产率得到SnCl4 * 2 triphenylphosphine
  参考文献：
  名称：

  Muratova, A. A.; Sobanova, O. B.; Yarkova, E. G., Journal of general chemistry of the USSR, 1980, vol. 50, p. 579 - 584

  摘要：

  DOI：

文献信息

• Reactions of the pentachlorostannate(<scp>IV</scp>) anion with Lewis bases, and Mössbauer data for some adducts of the type pentachlorostannate(<scp>IV</scp>)–base (1/1)
  作者：Desmond Cunningham、James Finnegan、John D. Donaldson、Malcolm J. Frazer

  DOI：10.1039/dt9770000162

  日期：——

  Reactions of tetraethylammonium pentachlorostannate(IV) with a variety of Lewis bases have been investigated. Those with acetonitrile, pyridine, tetrahydrofuran, and salicylaldehyde as base (L) result in the formation of adducts [NEt4][SnCl5·L], while with trimethylamine, 2,2′-bipyridyl (bipy), phosphines, arsines, phosphine oxides, and arsine oxides the products are [NEt4]2[SnCl6] and 1:2 adducts

  已经研究了五氯锡酸四乙铵（IV）与多种路易斯碱的反应。以乙腈，吡啶，四氢呋喃和水杨醛为碱（L）的那些会导致形成加合物[NEt 4 ] [SnCl 5 ·L]，而与三甲胺，2,2'-联吡啶（bipy），膦、,、氧化膦和氧化砷的产物是[NEt 4 ] 2 [SnCl 6 ]和四氯化锡（IV）的1：2加合物（在联吡啶的情况下为1：1加合物）。与喹啉-8-醇（Hquin），戊烷-2,4-二酮（Hpd）和对pol酮（Htrop）的反应导致HCl的消除和[NEt 4 4] [SnCl 4的形成L']（L'= quin，pd或trop）。加合物[NEt 4 ] [SnCl 5 ·L]的Mössbauer四极分裂数据与从点电荷模型预测的数据一致。
• Yashina, N. S.; Gefel', E. I.; Kosina, A. N., Koordinatsionnaya Khimiya, 1985, vol. 11, p. 947 - 954
  作者：Yashina, N. S.、Gefel', E. I.、Kosina, A. N.、Petrosyan, V. S.、Reutov, O. A.

  DOI：——

  日期：——
• Electron density redistribution on complexation in non-transition element complexes
  作者：O.Kh. Poleshchuk、B. Nogaj、G.N. Dolenko、V.P. Elin

  DOI：10.1016/0022-2860(93)80185-x

  日期：1993.8

  Complexes of tin, antimony, silicon, germanium, iodine, boron and titanium halogenides with organic ligands were investigated using nuclear quadrupole resonance (NQR) and X-ray fluorescence spectroscopies, and Mossbauer effect and quantum-chemical calculations. A discussion of results which we obtained previously as well as literature data is included. The correlations between Cl-35 NQR and ClKalpha line shifts in SnCl4L2, SbCl5L and TiCl4L2 complexes were obtained. The geometry of the acceptor was found to influence the value of the effective charge on the chlorine atom (q(Cl)) in SnCl4L2 complexes, but not to influence the chlorine atom in TiCl4L2 complexes. Values of q(Sn) and q(Sb) were calculated from Mossbauer isomer shifts in the SnCl4L2 and SbCl5L complexes. Electron-density transfer from the ligand to the vacant d orbital of the central atom on complexation was observed.