[Cu(2,2':6',2''-terpyridine)(C6H4(PO3H)2)]*H2O | 935661-52-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: [Cu(2,2':6',2''-terpyridine)(C6H4(PO3H)2)]*H2O
• 英文别名: [Cu(2,2':6',2''-terpy)(C6H4(PO3H)2)]*H2O
• CAS: 935661-52-2
• 化学式: C₂₁H₁₇CuN₃O₆P₂*H₂O
• 分子量: 550.891
• InChiKey: JNSKYYDZDDJPSH-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  α,α,α-三联吡啶 、 copper(ll) sulfate pentahydrate 、 1,2-双(二甲氧基磷基)-苯 、 水 在 HCl 作用下， 以 水 为溶剂， 以99%的产率得到[Cu(2,2':6',2''-terpyridine)(C6H4(PO3H)2)]*H2O
  参考文献：
  名称：

  Solid state coordination chemistry of organodiphosphonates with copper(II) and auxilliary aromatic nitrogen heterocyclic ligands

  摘要：

  The hydrothermal reactions of CUSO4 - 5H(2)O, a phosphonate ligand and an appropriate aromatic nitrogen heterocycle yield a series of materials of the Cu(II)/phosphonate/nitrogen ligand donor family. Two of the materials [Cu(2,2'-bpy)(HO3PCH2CH2CH2PO3H)] (1) and [Cu(4,4'-bpy)(H2O)(2)(HO3PCH2CH2CH2CH2PO3H)] (2) are two-dimensional, while [{Cu(2,2'-bpy)}(2)(O3PC6H4PO3)](.) 8H(2)O (3 (.) 8H(2)O) is three-dimensional. When 1,3,5-benzenetricarboxylic acid is introduced as a reactant, the one-dimensional material [Cu(2,2'-bpy){OC6H2(CO2H)(3)} (HOPC6H5)] (4) is isolated. This is an example of an in situ hydrothermal ligand transformation in which the 1,3,5-benzene tricarboxylic acid is hydroxylated to give 1,3,5-benzene tricarboxylic acid-2-hydroxide. Compound 5 [Cu(terpy)(HO3PC6H4PO3H] is molecular. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2006.08.022