1,8-bis(nicotinyloxy)-9,10-anthracenedione | 953793-70-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 1,8-bis(nicotinyloxy)-9,10-anthracenedione
• 英文别名: 1,8-bis(nicotinyloxy)anthracene-9,10-dione；[9,10-Dioxo-8-(pyridine-3-carbonyloxy)anthracen-1-yl] pyridine-3-carboxylate
• CAS: 953793-70-9
• 化学式: C₂₆H₁₄N₂O₆
• 分子量: 450.407
• InChiKey: RXXBWTAHSGLCLW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  34
• 可旋转键数：
  6
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  113
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  dichlorotetrakis(dimethylsulfoxide)ruthenium(II) 、 1,8-bis(nicotinyloxy)-9,10-anthracenedione 以 苯 为溶剂， 以75%的产率得到[(1,8-bis(nicotinyloxy)-9,10-anthracenedione)RuCl2(DMSO)2]
  参考文献：
  名称：

  Complexation, crystallography, and electrochemistry of new chelating nicotinyl and thiazolyl anthraquinone ligands

  摘要：

  Chelating anthraquinone ligands that contain nicotinyl and thiazolyl binding units have been synthesized. The complexation chemistry of these new ligands has also been explored using cadmium(II), lead(II), and ruthenium(II). The nicotinic substituted anthraquinone acts as a bidentate ligand, while the thiazolyl substituted anthraquinone binds in a tetradentate arrangement, not previously observed. Due to steric limitations, the number of these ligands that can coordinate to metal centers appears limited to bis-substituted products. Crystallographic data for both the free ligands and the cadmium and lead complexes are reported. Electrochemical data indicate that interaction does not take place between the intraannular carbonyl group and the neighboring metal centers within these complexes. (C) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2007.05.012

文献信息

• Chelating, bridging, and chain structures within Ag(I) and Cu(I) complexes of bis(nicotinyloxy), bis(isonicotinyloxy), and bis(pyrimidine-5-carboxyloxy)-1,8-disubstituted anthraquinone ligands
  作者：Stephanie S. Peterson、Tishal Kirby、Mariappan Kadarkaraisamy、Richard M. Hartshorn、Andrew G. Sykes

  DOI：10.1016/j.poly.2009.06.024

  日期：2009.9

  Reaction of Ag(I) and Cu(I) [M(NCCH3)(4)]X (X = BF4- and PF6-) salts with 1,8-bis(nicotinyloxy)anthracene-9,10-dione (1), 1,8-bis(isonicotinyloxy)anthracene-9,10-dione (2), and 1,8-bis(pyrimidine-5-carboxyloxy)anthracene-9,10-dione (3), yield new chelating and bridging complexes and two new coordination polymers. The bridging capabilities of ligands 1 and 2 have not been demonstrated before, and ligand 1, by itself, has the flexibility to produce either chelated or bridged structures and an unusual ladder coordination polymer. The tetradentate ligand 3 also produces a one-dimensional coordination polymer in the presence of one equivalent of Ag(I). All complexes have been characterized by X-ray crystallography. (C) 2009 Elsevier Ltd. All rights reserved.