| 85571-01-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 85571-01-3
• 化学式: Br*C₁₆H₁₈CoN₂O₄
• 分子量: 441.227
• InChiKey: GRRWIBMNWBQVDV-XWTYAXFOSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  potassium thioacyanate 、 以 甲醇 、 水 为溶剂， 生成
  参考文献：
  名称：

  Yamada, Shoichiro; Nishikawa, Hiroaki; Ohno, Emiko, Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1983, vol. 13, p. 233 - 248

  摘要：

  DOI：
• 作为产物：
  描述：

  sodium bromide 、 [N,N'-bis(salicylidene)ethane-1,2-diaminato]cobalt(II) 在 双氧水 作用下， 以 甲醇 、 水 、 溶剂黄146 为溶剂， 生成
  参考文献：
  名称：

  Yamada, Shoichiro; Nishikawa, Hiroaki; Ohno, Emiko, Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1983, vol. 13, p. 233 - 248

  摘要：

  DOI：

文献信息

• Cyanide bridged di- and tri-nuclear complexes with central Cr(III)-, Mn(III)- and Co(III)-salen units
  作者：R. Appelt、H. Vahrenkamp

  DOI：10.1016/s0020-1693(02)01550-5

  日期：2003.7

  Reactions between M(salen)X (M=Cr(III), Mn(III), Co(III)) and LnM'-CN (LnM'=Cp(CO)(2)Fe, Cp(dppe)Fe, Cp(PPh3)(2)Ru, (CO)(5)Cr-) have yielded 4 dinuclear and 11 symmetrical trinuclear complexes with LnM'-CN-M(salen) arrangements. The heterotrinuclear complexes with Fe-CN-Cr-NC-Ru and Fe-CN-Cr-NC-Cr arrays and one isomeric Fe-NC-Co-CN-Fe complex were also obtained. Their IR, electrochemical and UV-Vis data were recorded and compared, including those of the corresponding Fe(III)salen complexes. Characteristic differences between the systems with empty (Cr, Co) and occupied (Mn, Fe) e(g) levels at the central M(III)salen units were observed. The tendency to support M'-C(CN) back bonding was found to decrease in the sequence Mnapproximate toFemuch greater thanCr>Co for the central M(III)salen units. The cyclic voltammograms indicate long range electronic interactions between the terminal metals in the trinuclear complexes. The UV-Vis data point to a metal-metal charge transfer from the terminal to the central metals. the energy required for which increases in the sequence Mnapproximate toFemuch less thanCrapproximate toCo. (C) 2003 Elsevier Science B.V. All rights reserved.