N,N'-bisphenyl-9,9-dioctyl-9H-fluorene-2,7-diamine | 915031-04-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 芴
• 英文名称: N,N'-bisphenyl-9,9-dioctyl-9H-fluorene-2,7-diamine
• 英文别名: 9,9-dioctyl-2-N,7-N-diphenylfluorene-2,7-diamine
• CAS: 915031-04-8
• 化学式: C₄₁H₅₂N₂
• 分子量: 572.877
• InChiKey: XXQJDLGYMGRSLK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  15.1
• 重原子数：
  43
• 可旋转键数：
  18
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.41
• 拓扑面积：
  24.1
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  N,N'-bisphenyl-9,9-dioctyl-9H-fluorene-2,7-diamine 、 N-[1,1'-联苯基]-4-基-N-(4'-氯-[1,1'-联苯]-4-基)-[1,1'-联苯]-4-胺 在 tris-(dibenzylideneacetone)dipalladium(0) 、 三叔丁基膦 sodium t-butanolate 作用下， 以 甲苯 为溶剂， 反应 8.0h， 以23%的产率得到9,9-dioctyl-2-N,7-N-diphenyl-2-N,7-N-bis[4-[4-(4-phenyl-N-(4-phenylphenyl)anilino)phenyl]phenyl]fluorene-2,7-diamine
  参考文献：
  名称：

  WO2006/120859

  摘要：

  公开号：
• 作为产物：
  描述：

  苯胺 、 9,9-二辛基-2,7-二溴代芴 在 palladium diacetate 1,1'-双(二苯基膦)二茂铁 、 sodium t-butanolate 作用下， 以 甲苯 为溶剂， 以98.8%的产率得到N,N'-bisphenyl-9,9-dioctyl-9H-fluorene-2,7-diamine
  参考文献：
  名称：

  Interface engineering for solid-state dye-sensitised nanocrystalline solar cells: the use of an organic redox cascade

  摘要：

  我们展示了在纳米结构二氧化钛/染料/聚合物/分子空穴传输多层界面上形成的电荷转移级联。当聚合物层的电离电位超过分子空穴传输层的电离电位时，该界面的电荷重组动力学将被延缓。

  DOI：

  10.1039/b513180d

文献信息

• LOW-MOLECULAR COMPOUND, POLYMER, ELECTRONIC-DEVICE MATERIAL, COMPOSITION FOR ELECTRONIC DEVICE, ORGANIC ELECTROLUMINESCENT ELEMENT, ORGANIC SOLAR CELL ELEMENT, DISPLAY AND LIGHTING
  申请人：Urano Toshiyuki

  公开号：US20120193617A1

  公开（公告）日：2012-08-02

  A subject for the invention is to provide compounds where a film formation can be made by a wet film formation method, a heating temperature at the film formation is low, the film formed therefrom has high stability, and the other layers can be laminated thereon by a wet film formation method or another method. The compounds are usable as a material for electronic device which decreases little in charge transport efficiency or luminescent efficiency and which have excellent driving stability. The invention resides in a compound and a polymer which are characterized by having a elimination group of a specific structure and in an organic compound characterized by having a elimination group having a low elimination temperature.
• POLYMERS CONTAINING THERMALLY DISSOCIABLE AND SOLUBLE GROUPS AND THE USE OF SUCH POLYMERS AS ORGANIC ELECTROLUMINESCENT MATERIALS
  申请人：URANO Toshiyuki

  公开号：US20140299864A1

  公开（公告）日：2014-10-09

  A polymer, a luminescent material, and the likes are provided, wherein a film can be formed by a wet film-forming method, the film formed has a high stability, and is capable of being laminated with other layers by a wet film-forming method or another method, which are less decrease in charge transportation efficiency or luminescent efficiency, and attain an excellent driving stability. The polymer has a thermally dissociable and soluble group.
• MATERIALS FOR ELECTRONIC DEVICES
  申请人：Merck Patent GmbH

  公开号：US20200216605A1

  公开（公告）日：2020-07-09

  The present application relates to a polymer containing at least one structural unit of a formula (I). The polymer is suitable for use in an electronic device.
• US8795849B2
  申请人：——

  公开号：US8795849B2

  公开（公告）日：2014-08-05