methylene bis(n-butanesulfonate) | 1264194-66-2

• 分子结构分类: 有机化合物
• 英文名称: methylene bis(n-butanesulfonate)
• 英文别名: Butylsulfonyloxymethyl butane-1-sulfonate
• CAS: 1264194-66-2
• 化学式: C₉H₂₀O₆S₂
• 分子量: 288.386
• InChiKey: HHWYDTHGFUYPNV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.7
• 重原子数：
  17
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  104
• 氢给体数：
  0
• 氢受体数：
  6

文献信息

• PROCESS FOR PRODUCTION OF BIS-QUATERNARY AMMONIUM SALT, AND NOVEL INTERMEDIATE
  申请人：Okamoto Kuniaki

  公开号：US20120130107A1

  公开（公告）日：2012-05-24

  Object To provide a method for producing a bis-quaternary ammonium salt efficiently and a novel synthetic intermediate thereof. Solution The present invention relates to a method for producing a bis-quaternary ammonium salt represented by a general formula [3] which comprises reacting a disulfonic acid ester represented by a general formula [1] (in the formula, definitions of two R 1 's and T are as described in claim 1 ) with a tertiary amine represented by a general formula [2] (in the formula, definitions of R 3 to R 5 are as described in claim 1 ), and a disulfonic acid ester represented by a general formula [1′] (in the formula, two R 16 's represent independently a halogen atom or a C1-C3 fluoroalkyl group, and two m's represent independently an integer of 1 to 5).

  提供一种高效生产双季铵盐和其新型合成中间体的方法。本发明涉及一种生产由通用式[3]表示的双季铵盐的方法，包括将由通用式[1]表示的二磺酸酯（在该式中，两个R1和T的定义如权利要求1中所述）与由通用式[2]表示的三级胺（在该式中，R3到R5的定义如权利要求1中所述）以及由通用式[1']表示的二磺酸酯（在该式中，两个R16独立表示卤原子或C1-C3氟烷基，两个m独立表示1至5的整数）反应。
• Bis-esters of 1,1-alkanediols with 6-beta-hydroxymethylpenicillanic acid 1,1-dioxide and beta-lactam antibiotics
  申请人：PFIZER INC.

  公开号：EP0061313A2

  公开（公告）日：1982-09-29

  Novel bis-Esters of 1,1-alkanediols with 6- beta(hydroxymethyl)penicillanic acid 1,1-dioxide and 6- betaacylaminopenicillanic acids are useful as antibacterial agents. Novel intermediates useful for the preparation of these compounds include: haloalkyl, alkylsulfonyloxyalkyl and arylsulfonyloxyalkyl esters of 6-beta-(hydroxymethyl)penicillanic acid and its 1-oxide and 1,1-dioxide; 6-beta-aminopenicillanoyloxyalkyl and 6-beta-(N-protected-D-2-amino-2-phenylacetamido and 2-[4-hydroxyphenyl]acetamido) penicillanoyloxyalkyl esters of 6-beta-(hydroxymethyl)penicillanic acid 1,1-dioxide; and haloalkyl, alkylsulfonyloxyalkyl and arylsulfonyloxyalkyl esters of the 6-bromo-6-(hydroxymethyl)penicillanic acids.

  1,1-烷二醇与 6-β（羟甲基）青霉烷酸 1,1-二氧化物和 6-β-乙酰氨基青霉烷酸的新型双酯可用作抗菌剂。用于制备这些化合物的新型中间体包括6-beta-(hydroxymethyl)penicillanic acid 及其 1-oxide 和 1,1-dioxide 的卤代烷基、烷基磺酰氧基烷基和芳基磺酰氧基烷基酯；6-beta-(羟甲基)青霉烷酸 1,1-二氧化物的 6-beta-氨基青霉烷酰氧基烷基和 6-beta-(N-保护-D-2-氨基-2-苯乙酰胺基和 2-[4-羟基苯基]乙酰胺基)青霉烷酰氧基烷基酯；以及 6-溴-6-(羟甲基)青霉烷酸的卤代烷基、烷基磺酰氧基烷基和芳基磺酰氧基烷基酯。
• Novel disulfonic acid ester as an additive for an electrolyte for a lithium secondary battery
  申请人：Wako Pure Chemical Industries, Ltd.

  公开号：EP2821395A2

  公开（公告）日：2015-01-07

  Object To provide a method for producing a bis-quaternary ammonium salt efficiently and a novel synthetic intermediate thereof. Solution The present invention relates to a method for producing a bis-quaternary ammonium salt represented by a general formula [3] which comprises reacting a disulfonic acid ester represented by a general formula [1] (in the formula, definitions of two R1's and T are as described in Claim 1) with a tertiary amine represented by a general formula [2] (in the formula, definitions of R3 to R5 are as described in Claim 1), and a novel disulfonic acid ester represented by a general formula [1'] (in the formula, two R16's represent independently a halogen atom or a C1-C3 fluoroalkyl group, and two m's represent independently an integer of 1 to 5) as an additive for an electrolyte for a lithium secondary battery.

  目的 提供一种高效生产双季铵盐的方法及其新型合成中间体。 本发明涉及一种生产通式[3]代表的双季铵盐的方法，该方法包括将通式[1]代表的二磺酸酯（式中，两个 R1 和 T 的定义如权利要求 1 所述）与通式[2]代表的叔胺（式中、R3至R5的定义如权利要求1所述），以及通式[1']代表的新型二磺酸酯（式中，两个R16独立地代表卤素原子或C1-C3氟烷基，两个m独立地代表1至5的整数），作为锂二次电池电解液的添加剂。
• US4342768A
  申请人：——

  公开号：US4342768A

  公开（公告）日：1982-08-03
• US4376076A
  申请人：——

  公开号：US4376076A

  公开（公告）日：1983-03-08