2-(Dimethoxymethyl)biphenyl | 127921-33-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-(Dimethoxymethyl)biphenyl
• 英文别名: 1-(Dimethoxymethyl)-2-phenylbenzene
• CAS: 127921-33-9
• 化学式: C₁₅H₁₆O₂
• 分子量: 228.291
• InChiKey: BCCNTWSBUIVXFE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  17
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-(Dimethoxymethyl)biphenyl 在 盐酸 作用下， 以 乙醚 为溶剂， 生成 联苯-2-甲醛
  参考文献：
  名称：

  通过烷基联苯的阳极甲氧基化反应合成苯基取代的环己-1,4-二烯和环己-2,5-二烯

  摘要：

  在以下条件下进行的一系列烷基联苯（2-，3-，4-甲基联苯，3,3'-，4,4'-二甲基联苯，4-乙基联苯和4,4'-二叔丁基联苯）的阳极甲氧基化作用恒定电流强度在相应的电子进行酸性水解后，在两个电子的过程中提供了多个顺/反式环己-1,4-二烯，在四个电子过程中提供了多个环己-2,5-二烯。环己-1，4-二烯缩酮。在某些情况下，还获得了侧链取代产物。提出了可能的机制。

  DOI：

  10.1016/s0040-4020(01)90078-x
• 作为产物：
  描述：

  联苯-2-甲醛 、 2,2-二甲氧基丙烷 在 对甲苯磺酸 作用下， 反应 18.0h， 以89%的产率得到2-(Dimethoxymethyl)biphenyl
  参考文献：
  名称：

  The preparation of 9-alkylthiofluorenes from biphenyl-2-carboxaldehydes

  摘要：

  DOI：

  10.1016/s0040-4039(01)93368-4

文献信息

• ACTIVE ESTER COMPOUND AND COMPOSITION AND CURED PRODUCT OBTAINED USING THE SAME
  申请人：DIC Corporation

  公开号：US20200207700A1

  公开（公告）日：2020-07-02

  The present invention aims to provide a means by which a cured product to be obtained has a low dielectric loss tangent and higher heat resistance. Specifically, provided are an active ester compound represented by chemical formula (1): (where in chemical formula (1), Ar 1 is a substituted or unsubstituted first aromatic ring group, and each Ar 2 is independently a substituted or unsubstituted second aromatic ring group, in which at least one of Ar 1 and Ar 2 has an unsaturated bond-containing substituent, and n is an integer of 2 or 3), a curable composition containing the active ester compound, and a cured product thereof.

  本发明旨在提供一种手段，通过该手段可以获得具有低介电损耗正切和更高耐热性的固化产品。具体地，提供了一种由化学式（1）表示的活性酯化合物：（其中，在化学式（1）中，Ar1是取代或未取代的第一芳香环基团，每个Ar2独立地是取代或未取代的第二芳香环基团，其中至少一个Ar1和Ar2具有含有不饱和键的取代基，n是2或3的整数），以及包含活性酯化合物的可固化组合物和其固化产物。
• ADAMANTANE DERIVATIVE, RESIN COMPOSITION CONTAINING SAME, AND OPTOELECTRONIC MEMBER AND SEALING AGENT FOR ELECTRONIC CIRCUIT USING THOSE
  申请人：Idemitsu Kosan Co., Ltd.

  公开号：EP1985616A1

  公开（公告）日：2008-10-29

  Disclosed is an adamantane derivative which provides a cured product excellent in optical characteristics such as transparency and light resistance, long-term heat resistance, electrical characteristics such as and dielectric constant, and low water absorption. Also disclosed are a resin composition containing the adamantane derivative, a sealing agent for electronic circuits, optical electronic member, semiconductor device and copper-clad laminate all using the resin composition, and a radiation-sensitive resin composition which contains the above-mentioned adamantane derivative as a crosslinking agent. Specifically disclosed are an adamantane derivative represented by the formula (I-1) below, a resin composition containing the adamantane derivative, a sealing agent for electronic circuits, optical electronic member, semiconductor device and copper-clad laminate, all using the resin composition, and a radiation-sensitive resin composition which contains the above-mentioned adamantane derivative as a crosslinking agent.

  本发明涉及一种金刚烷衍生物，其提供了在光学特性（如透明度和耐光性）、长期耐热性、电学特性（如介电常数）和低吸水性等方面表现出色的固化产物。本发明还涉及一种含有金刚烷衍生物的树脂组合物，以及使用该树脂组合物的电子电路密封剂、光电子元件、半导体器件和铜覆盖层层压板，以及一种辐射敏感的树脂组合物，其中包含上述金刚烷衍生物作为交联剂。具体公开了以下公式（I-1）所表示的金刚烷衍生物，以及含有该金刚烷衍生物的树脂组合物、电子电路密封剂、光电子元件、半导体器件和铜覆盖层层压板，以及含有上述金刚烷衍生物作为交联剂的辐射敏感的树脂组合物。
• Process for producing aromatic aldehyde
  申请人：Kawazoe Kentaro

  公开号：US20070004934A1

  公开（公告）日：2007-01-04

  A process for producing an aromatic aldehyde compound represented by a general formula (3): (wherein R′ and n are as defined below), which comprises reacting a benzyl compound represented by a general formula (1): (wherein R may represents hydrogen atom, n represents an integer of 1 to 6, and R′ may be the same or different and represent a hydrogen atom or an alkyl gorup, an alkyl group or a phenyl group which may have a substituent) with an oxy-compound of bromine represented by the formula (2): MBrO m (2) (wherein M represents a hydrogen atom or a metal atom, and m represents an integer of 1 to 3) in the presence of an acid catalyst. According to this method, an aromatic aldehyde compound can be produced in high selectivity by a simple operation without using an expensive catalyst or transition metal.

  一种制备通式（3）所表示的芳香醛化合物的方法，包括将通式（1）所表示的苄基化合物（其中R可能代表氢原子，n表示1至6的整数，R'可以相同或不同，代表氢原子或具有取代基的烷基、苯基或烷基苯基）与通式（2）所表示的溴氧化物反应（其中M代表氢原子或金属原子，m表示1至3的整数），在酸催化剂的存在下进行。根据该方法，可以通过简单的操作，在不使用昂贵的催化剂或过渡金属的情况下高选择性地制备芳香醛化合物。
• POLYPHENOL RESIN, PROCESS FOR ITS PRODUCTION, EPOXY RESIN COMPOSITION AND ITS USE
  申请人：Nippon Kayaku Kabushiki Kaisha

  公开号：EP1323761A1

  公开（公告）日：2003-07-02

  An object of the present invention is to provide an epoxy resin composition which has high flexibility, can be molded to a thin membrane, and can become a noninflammable cured product. The present invention comprises a polyphenol compound obtained by reacting to condense phenol with bischloromethyl biphenyl or bismethoxymethyl biphenyl, removing unreacted phenol and then reacting with BCMB again, wherein the polyphenol compound has a weight-average molecular weight of 3,000 or more as determined by GPC, and using the polyphenol compound as an agent for curing an epoxy resin.

  本发明的目的是提供一种环氧树脂组合物，该组合物具有高柔韧性，可模塑成薄 膜，并可成为不易燃的固化产品。 本发明包括一种多酚化合物，它是通过将苯酚与双氯甲基联苯或双甲氧基甲基联苯反应缩合，除去未反应的苯酚，然后再与 BCMB 反应而得到的，其中多酚化合物经 GPC 测定的重量平均分子量为 3,000 或更高，并将该多酚化合物用作环氧树脂的固化剂。
• SILICON COMPOUND CONTAINING EPOXY GROUP AND THERMOSETTING RESIN COMPOSITION
  申请人：NIPPON KAYAKU KABUSHIKI KAISHA

  公开号：EP1593703A1

  公开（公告）日：2005-11-09

  The present invention relates to an epoxy group-containing silicon compound which is obtained by condensing at least one epoxy group-containing alkoxy silicon compound per se represented by the general formula (1a): R1aSi(OR2)3, wherein R1a denotes a substituent having an epoxy group and R2 denotes an alkyl group having at most 4 carbons, or said compound and at least one substituted alkoxy silicon compound represented by the general formula (1b): R1bSi(OR3)3, wherein R1b denotes an alkyl group having at most 10 carbons, an aryl group or an unsaturated aliphatic residue and R3 denotes an alkyl group having at most 4 carbons, in the presence of a basic catalyst.

  本发明涉及一种含环氧基的硅化合物，它是通过缩合至少一种本身由通式(1a)表示的含环氧基的烷氧基硅化合物而得到的：R1aSi(OR2)3，其中 R1a 表示具有环氧基的取代基，R2 表示具有至多 4 个碳原子的烷基，或上述化合物和至少一种由通式(1b)表示的取代烷氧基硅化合物：R1bSi(OR3)3，其中 R1b 表示具有至多 10 个碳原子的烷基、芳基或不饱和脂肪族残基，R3 表示具有至多 4 个碳原子的烷基。