(4S)-5-((tert-butyldimethylsilyl)oxy)-3-ethyl-4-(4-methylphenylsulfonamido)-1-phenylpent-1-yn-3-yl benzoate | 1333921-06-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (4S)-5-((tert-butyldimethylsilyl)oxy)-3-ethyl-4-(4-methylphenylsulfonamido)-1-phenylpent-1-yn-3-yl benzoate
• CAS: 1333921-06-4
• 化学式: C₃₃H₄₁NO₅SSi
• 分子量: 591.844
• InChiKey: AYGBLPCLZGEXRM-JKNLKRECSA-N

反应信息

• 作为反应物：
  描述：

  (4S)-5-((tert-butyldimethylsilyl)oxy)-3-ethyl-4-(4-methylphenylsulfonamido)-1-phenylpent-1-yn-3-yl benzoate 、 3-溴丙烯 在 sodium hydride 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 生成 (4S)-4-(N-allyl-4-methylphenylsulfonamido)-5-((tert-butyldimethylsilyl)oxy)-3-ethyl-1-phenylpent-1-yn-3-yl benzoate 、 (4S)-4-(N-allyl-4-methylphenylsulfonamido)-5-((tert-butyldimethylsilyl)oxy)-3-ethyl-1-phenylpent-1-yn-3-yl benzoate
  参考文献：
  名称：

  Gold-Catalyzed Tandem 1,3-Migration/[2 + 2] Cycloaddition of 1,7-Enyne Benzoates to Azabicyclo[4.2.0]oct-5-enes

  摘要：

  A synthetic method that relies on gold(I)-catalyzed tandem l,3-migration/[2 + 2] cycloaddition of 1,7-enyne benzoates to prepare azabicyclo [4.2.0] oct-5-enes is described.

  DOI：

  10.1021/ja2052304