2-[2-[2,4,6-Triethyl-3,5-bis(2-pyridin-2-ylethyl)phenyl]ethyl]pyridine | 745016-09-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 2-[2-[2,4,6-Triethyl-3,5-bis(2-pyridin-2-ylethyl)phenyl]ethyl]pyridine
• CAS: 745016-09-5
• 化学式: C₃₃H₃₉N₃
• 分子量: 477.693
• InChiKey: OQFGJTRSOZMELC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.9
• 重原子数：
  36
• 可旋转键数：
  12
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.36
• 拓扑面积：
  38.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  双(乙腈)氯化钯(II) 、 2-[2-[2,4,6-Triethyl-3,5-bis(2-pyridin-2-ylethyl)phenyl]ethyl]pyridine 以 甲醇 、 二甲基亚砜 为溶剂， 生成
  参考文献：
  名称：

  Supramolecular and Coordination Polymer Complexes Supported by a Tripodal Tripyridine Ligand Containing a 1,3,5-Triethylbenzene Spacer

  摘要：

  By combining a tripodal tripyridine ligand containing a 1,3,5triethylbenzene spacer (L) with several divalent transition-metal chlorides, we have selectively prepared a capsule-type supramolecular complex, [Pd-3(II)(L)(2)Cl-6].2H(2)O and one-dimensional (1D) coordination polymer complexes, ([Cu-II(L)Cl-2].C2H5OH)(n), ([Co-3(II)(L)(2)Cl-6].2CH(2)O(2))(n), and ([Zn-3(II)(L)(2)Cl-6].2H(2)O)(n), with a zigzag polymer chain, a linear polymer chain, and a ladder polymer chain structure, respectively. All the structures were established in detail by singlecrystal X-ray diffraction analysis, and the factors inducing the structural differences among the complexes are discussed by taking account of the differences in coordination geometry (square planar vs tetrahedral) as well as metal-ligand binding strength in the complexes.

  DOI：

  10.1021/ic049468j

文献信息

• Structure and photoluminescence property of two-dimensional coordination polymer complexes involving CuI6X6(X = Cl, Br, I) hexagon prism cluster supported by a tripodal tripyridine ligand with 1,3,5-triethylbenzene spacer
  作者：Hiromi Ohi、Yoshimitsu Tachi、Takashi Kunimoto、Shinobu Itoh

  DOI：10.1039/b508747c

  日期：——

  Treatment of cuprous halide (CuIX, X = Cl, Br, and I) and a tripodal tripyridine ligand (L) consisting of a 1,3,5-triethylbenzene spacer gave a unique two-dimensional (2D) polymer sheet structure involving a rare CuI6X6 hexagon prism cluster unit, which exhibits intense fluorescence around 448–476 nm.

  卤化亚铜（CuIX，X = Cl、Br和I）和三吡啶配体（L）由1,3,5-三乙基苯间隔物组成，其处理方式产生了独特的二维（2D）聚合物片层结构，其中包含罕见的CuI6X6六边形棱柱簇单元，该单元在448-476纳米附近表现出强烈的荧光。