(6-phenyl-2-((2,6-diisopropylphenyl)iminomethyl)phenoxide)Ni(Ph)(PPh3) | 210096-27-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (6-phenyl-2-((2,6-diisopropylphenyl)iminomethyl)phenoxide)Ni(Ph)(PPh3)
• 英文别名: [[6-CHN(2,6-(i-Pr)2C6H3)-2-Ph-C6H3O-κ2-N,O]Ni(Ph)(PPh3)]；(sal)Ni(Ph)(PPh3)
• CAS: 210096-27-8
• 化学式: C₄₉H₄₆NNiOP
• 分子量: 754.574
• InChiKey: SFTLGNGOODVRME-OAZWWVGISA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  3,4-二氢异喹啉 、 (6-phenyl-2-((2,6-diisopropylphenyl)iminomethyl)phenoxide)Ni(Ph)(PPh3) 在 CuCl 作用下， 以 苯 为溶剂， 以84%的产率得到(6-phenyl-2-((2,6-diisopropylphenyl)iminomethyl)phenoxide)Ni(Ph)(3,4-dihydroisoquinoline)
  参考文献：
  名称：

  Synthesis of neutral nickel–methyl complexes with monodentate imines and their sequential insertion of carbon monoxide and imine

  摘要：

  Neutral nickel-imine complexes of the form (N boolean AND O)Ni(R)((RN)-N-1=C(H)R-2) (N boolean AND O = salicylaldiminato; R = CH3, Ph; R-1 = alkyl; R-2 = aryl) can be prepared by the reaction of (tmeda)Ni(CH3)(2), imine and the corresponding salicylaldiminato ligand. The addition of carbon monoxide to these complexes lead to the in situ generation of the corresponding nickel-acyl complexes. With N-methyl or N-benzyl substituted imines, these complexes reductively eliminate the phenolic and acyl ligands to generate esters. However, the less sterically encumbered 3,4-dihydroisoquinoline can couple with the nickel-acyl ligand to form 1,2-diamides in high yield. In situ H-1 NMR analysis suggests this reaction occurs via insertion of imine into the nickel-acyl bond to form a nickel-bound amide complex.[GRAPHICS](C) 2010 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2010.12.024

文献信息

• Reaction of Vinyl Chloride with Late Transition Metal Olefin Polymerization Catalysts
  作者：Stephen R. Foley、Robert A. Stockland、Han Shen、Richard F. Jordan

  DOI：10.1021/ja029823+

  日期：2003.4.1

  The reactions of vinyl chloride (VC) with representative late metal, single-site olefin dimerization and polymerization catalysts have been investigated. VC coordinates more weakly than ethylene or propylene to the simple catalyst (Me(2)bipy)PdMe(+) (Me(2)bipy = 4,4'-Me(2)-2,2'-bipyridine). Insertion rates of (Me(2)bipy)Pd(Me)(olefin)(+) species vary in the order VC > ethylene > propylene. The VC complexes

  已经研究了氯乙烯 (VC) 与代表性的后期金属、单中心烯烃二聚和聚合催化剂的反应。VC 与简单催化剂 (Me(2)bipy)PdMe(+) (Me(2)bipy = 4,4'-Me(2)-2,2'-bipyridine) 的协调比乙烯或丙烯更弱。(Me(2)bipy)Pd(Me)(烯烃)(+) 物种的插入率按 VC > 乙烯 > 丙烯的顺序变化。VC 复合物 (Me(2)bipy)Pd(Me)(VC)(+) 和 (alpha-diimine)Pd(Me)(VC)(+) (alpha-diimine = (2,6-(i)Pr (2)[bond]C(6)H(3))N[双键]CMeCMe[双键]N(2,6-(i)Pr(2)[bond]C(6)H(3)) ) 经历净 1,2 VC 插入和 β-Cl 消除以产生 Pd[键]Cl 物质和丙烯。（吡啶-双亚胺）MCl(2)/MAO 催化剂（M = Fe,