[Pd(2,6-(Ph2PCH2)2C6H3)(NMe2)] | 259256-86-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Pd(2,6-(Ph2PCH2)2C6H3)(NMe2)]
• 英文别名: dimethylazanide;[3-(diphenylphosphanylmethyl)benzene-2-id-1-yl]methyl-diphenylphosphane;palladium(2+)
• CAS: 259256-86-5
• 化学式: C₃₄H₃₃NP₂Pd
• 分子量: 624.01
• InChiKey: AKXFGTVHIGAJIC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.37
• 重原子数：
  38
• 可旋转键数：
  8
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  [Pd(2,6-(Ph₂PCH₂)2C₆H₃)(NHMe₂)](OTf) 在 lithium dicyclohexylamide 作用下， 以 氘代四氢呋喃 为溶剂， 生成 [Pd(2,6-(Ph2PCH2)2C6H3)(NMe2)]
  参考文献：
  名称：

  Preparation of the palladium(II) dimethylamide Pd(2,6-(Ph2PCH2)2C6H3)(NMe2) at low temperatures and its ligand exchange with the dicyclohexylamide

  摘要：

  The title complex Pd(2,6-(Ph2PCH2)(2)C6H3)(NMe2) (2) has been prepared from deprotonation of [Pd(2,6-(Ph2PCH2)(2)C6H3)(NHMe2)]OTf (1) by a stoichiometric amount of dicyclohexylamide anion at low temperatures. VT NMR experiments showed that 2 was stable below -10 degrees C, and slowly underwent decomposition to give a couple of unidentified species at elevated temperatures. However, the reaction of 1 with an excess of lithium dicyclohexylamide (> ten equivalents) generated the monomeric palladium(II) hydride (2,6-(Ph2PCH2)(2)C6H3)PdH (3). The reaction of (Ph2PCH2)(2)C6H3)Pd(OTf) with an excess of lithium dicyclohexylamide also produced the hydride. A d(8)-THF solution of 3 was stable for 16 h at ambient temperature. However, an attempt to isolate 3 resulted in the formation of a small amount of the hydride-bridged dipalladium [(Pd(2,6-(Ph2PCH2)(2)C6H3))(2)(mu-H)(+)] (4) and mostly decomposed species. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(99)00511-2