bis(2-methoxyethylindenyl)lanthanum tetrahydroborate | 313220-37-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: bis(2-methoxyethylindenyl)lanthanum tetrahydroborate
• 英文别名: boranuide;lanthanum(3+);1-(2-methoxyethyl)inden-1-ide
• CAS: 313220-37-0
• 化学式: C₂₄H₃₀BLaO₂
• 分子量: 500.218
• InChiKey: QUMJVURWNMLGBR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.04
• 重原子数：
  28
• 可旋转键数：
  6
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  sodium tetrahydroborate 、 La(1-(2-methoxyethyl)indenyl)2Cl 以 四氢呋喃 为溶剂， 以81%的产率得到bis(2-methoxyethylindenyl)lanthanum tetrahydroborate
  参考文献：
  名称：

  Stereoselective synthesis and structural characterization of rac-planar chiral bis(2-methoxyethylindenyl)lanthanum and yttrium tetrahydroborates

  摘要：

  Racemic planar chiral metallocenes bis(2-methoxyethylindenyl) yttrium and lanthanum tetrahydroborates (MeOCH2CH2C9H6)(2)Ln(mu(2)-H)(n)BH4-n (Ln = Y, n = 2 (1); Ln = La, n = 3, (2)) have been stereoselectively isolated in high yield by reaction of the corresponding lanthanocene chlorides with sodium borohydride in THF at room temperature. The two complexes have been fully characterized by elemental analyses, MS, H-1 NMR and IR spectra. The tetrahydroborate ion has been identified as slipped bidentate (mu(2)-H)(2)BH2 and tridentate (mu(2)-H)(3)BH ligands in 1 and 2, respectively. (C) 2000 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(00)00479-4