cholesteryl 4-(but-3-enyloxy)benzoate | 166047-62-7

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 类固醇和类固醇衍生物
• 英文名称: cholesteryl 4-(but-3-enyloxy)benzoate
• 英文别名: [(3S,8S,9S,10R,13R,14S,17R)-10,13-dimethyl-17-[(2R)-6-methylheptan-2-yl]-2,3,4,7,8,9,11,12,14,15,16,17-dodecahydro-1H-cyclopenta[a]phenanthren-3-yl] 4-but-3-enoxybenzoate
• CAS: 166047-62-7
• 化学式: C₃₈H₅₆O₃
• 分子量: 560.861
• InChiKey: LWCHOFORJFLXIV-IJJDISMQSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.9
• 重原子数：
  41
• 可旋转键数：
  12
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  4-(3-丁烯氧基)苯甲酸 在 吡啶 、 氯化亚砜 作用下， 以 四氢呋喃 为溶剂， 生成 cholesteryl 4-(but-3-enyloxy)benzoate
  参考文献：
  名称：

  Influence of Interim Alkyl Chain Length on Phase Transitions and Wide-Band Reflective Behaviors of Side-Chain Liquid Crystalline Elastomers with Binaphthalene Crosslinkings

  摘要：

  A series of side-chain polysiloxane liquid crystalline elastomers, E-Cm (where m is the number of carbon atoms in the interim alkyl groups, and m = 4, 6, 8, 10), with binaphthalene derivatives as crosslinkings, were designed and synthesized. The mesophase structures of these elastomers were dependent on the value of m. The elastomers with m <= 8 could form cholesteric (Ch) phases, while both smectic A and Ch phases could be formed for the elastomer with m = 10. Blue phases can be achieved when m >= 8. Besides, the helical twisting power (HTP) of all the elastomers exhibits a turning point with changing temperature. Both the turning temperature and HTP have an apparent dependence on the value of m. By adjusting the interim alkyl chain length in the elastomers, both visible and near-infrared light wide-band reflective films can be obtained. The broadband reflection mechanism was confirmed by SEM investigations.

  DOI：

  10.1021/ma300618t