Copper;imino(triphenyl)-lambda5-phosphane;diacetate | 371196-26-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Copper;imino(triphenyl)-lambda5-phosphane;diacetate
• 英文别名: copper;imino(triphenyl)-λ5-phosphane;diacetate
• CAS: 371196-26-8
• 化学式: C₄₀H₃₈CuN₂O₄P₂
• 分子量: 736.246
• InChiKey: TZJXIODGQLKDJR-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  5.0
• 重原子数：
  49
• 可旋转键数：
  8
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  128
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  Copper;imino(triphenyl)-lambda5-phosphane;diacetate 、 copper(II) acetate monohydrate 以 二氯甲烷 为溶剂， 生成 Dicopper;imino(triphenyl)-lambda5-phosphane;tetraacetate
  参考文献：
  名称：

  Copper(II) Acetate Complexes, [CuL_m(OAc)₂]_n (L = HNPPh₃), Stable in the Solid State Either as a Dimer (m = 1, n = 2) or a Monomer (m = 2, n = 1)

  摘要：

  The synthesis and X-ray structures of two novel copper(II) phosphinimine acetate complexes, monomeric Cu(HNPPh3)(2)(OAc)(2) and dimeric [Cu(HNPPh3)(OAc)(2)](2), are described. Intramolecular hydrogen bonding between acetate ligands and the imino hydrogen stabilizes Cu(HNPPh3)(2)(OAc)(2), whereas the copper(II) tetraacetato core of [Cu(HNPPh3)(OAc)(2)](2) possesses neither intra- nor intermolecular hydrogen bonding.[GRAPHICS]

  DOI：

  10.1021/ic0155636
• 作为产物：
  描述：

  Dicopper;imino(triphenyl)-lambda5-phosphane;tetraacetate 以 二氯甲烷 为溶剂， 生成 Copper;imino(triphenyl)-lambda5-phosphane;diacetate
  参考文献：
  名称：

  Copper(II) Acetate Complexes, [CuL_m(OAc)₂]_n (L = HNPPh₃), Stable in the Solid State Either as a Dimer (m = 1, n = 2) or a Monomer (m = 2, n = 1)

  摘要：

  The synthesis and X-ray structures of two novel copper(II) phosphinimine acetate complexes, monomeric Cu(HNPPh3)(2)(OAc)(2) and dimeric [Cu(HNPPh3)(OAc)(2)](2), are described. Intramolecular hydrogen bonding between acetate ligands and the imino hydrogen stabilizes Cu(HNPPh3)(2)(OAc)(2), whereas the copper(II) tetraacetato core of [Cu(HNPPh3)(OAc)(2)](2) possesses neither intra- nor intermolecular hydrogen bonding.[GRAPHICS]

  DOI：

  10.1021/ic0155636