(1,1,1-trichloro-2-methyl-2-propyl) 2-chloro-2-methylpropanoate | 98946-08-8

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: (1,1,1-trichloro-2-methyl-2-propyl) 2-chloro-2-methylpropanoate
• 英文别名: α-chloro-isobutyric acid-(2,2,2-trichloro-1,1-dimethyl-ethyl ester)；α-Chlor-isobuttersaeure-(2,2,2-trichlor-1,1-dimethyl-aethylester)；(1,1,1-trichloro-2-methylpropan-2-yl) 2-chloro-2-methylpropanoate
• CAS: 98946-08-8
• 化学式: C₈H₁₂Cl₄O₂
• 分子量: 281.994
• InChiKey: HHRKFOSKDLBQFQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  14
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.88
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  三氯叔丁醇 在 三氯化铝 、 溴苯 作用下， 生成 (1,1,1-trichloro-2-methyl-2-propyl) 2-chloro-2-methylpropanoate 、 alkaline earth salt of/the/ methylsulfuric acid
  参考文献：
  名称：

  Dichloromethylallyl Compounds. II. The Catalytic and Non-catalytic Substitution of Certain Chloroallylic Groups in the Ring and on the Oxygen in Phenols

  摘要：

  DOI：

  10.1021/ja01604a041

文献信息

• METHOD FOR PRODUCING UNSATURATED ACID AND/OR UNSATURATED ACID ESTER
  申请人：Asahi Glass Company, Limited

  公开号：US20150175520A1

  公开（公告）日：2015-06-25

  The present invention relates to a method for producing an unsaturated acid and/or an unsaturated acid ester, containing a process A of reacting a compound (1) represented by the following formula (1) at a temperature of 0° C. to 350° C. in the presence of a Brønsted acid catalyst and/or a Lewis acid catalyst, to prepare a compound (2) represented by the following formula (2); in which each of R 1 , R 2 and R 4 independently represents a hydrogen atom, a deuterium atom or an alkyl group; each of R 3 and R 5 independently represents a hydrogen atom or a deuterium atom; R 6 represents a hydrogen atom, a deuterium atom, or an alkyl group or an aryl group; and X represents a chlorine atom, a fluorine atom, a bromine atom, or an iodine atom.

  本发明涉及一种生产不饱和酸和/或不饱和酸酯的方法，包括在存在Brønsted酸催化剂和/或Lewis酸催化剂的条件下，以0°C至350°C的温度反应以下式(1)表示的化合物(1)，制备以下式(2)表示的化合物(2)的过程A；其中R1、R2和R4中的每一个独立地表示氢原子、氘原子或烷基基团；R3和R5中的每一个独立地表示氢原子或氘原子；R6表示氢原子、氘原子、烷基基团或芳基；X表示氯原子、氟原子、溴原子或碘原子。
• Method for producing unsaturated acid and/or unsaturated acid ester
  申请人：Asahi Glass Company, Limited

  公开号：US09238612B2

  公开（公告）日：2016-01-19

  The present invention relates to a method for producing an unsaturated acid and/or an unsaturated acid ester, containing a process A of reacting a compound (1) represented by the following formula (1) at a temperature of 0° C. to 350° C. in the presence of a Brønsted acid catalyst and/or a Lewis acid catalyst, to prepare a compound (2) represented by the following formula (2); in which each of R1, R2 and R4 independently represents a hydrogen atom, a deuterium atom or an alkyl group; each of R3 and R5 independently represents a hydrogen atom or a deuterium atom; R6 represents a hydrogen atom, a deuterium atom, or an alkyl group or an aryl group; and X represents a chlorine atom, a fluorine atom, a bromine atom, or an iodine atom.

  本发明涉及一种制备不饱和酸和/或不饱和酸酯的方法，包括通过在Brønsted酸催化剂和/或Lewis酸催化剂的存在下，在0℃至350℃的温度下反应以下式(1)所表示的化合物(1)，以制备以下式(2)所表示的化合物(2)的A过程；其中，R1、R2和R4各自独立地表示氢原子、氘原子或烷基；R3和R5各自独立地表示氢原子或氘原子；R6表示氢原子、氘原子、烷基或芳基；X表示氯原子、氟原子、溴原子或碘原子。
• PRODUCTION METHOD FOR CARBONATE COMPOUND AND METHACRYLATE OR ESTER THEREOF
  申请人：Asahi Glass Company, Limited

  公开号：US20160347905A1

  公开（公告）日：2016-12-01

  The present invention relates to a method for producing a carbonate compound and methacrylic acid or an ester thereof, containing a step (a1) of obtaining hexachloroacetone and hydrogen chloride from acetone and chlorine molecule, a step (a2) of obtaining a dialkyl carbonate and chloroform from hexachloroacetone and an alkyl alcohol, a step (b1) of obtaining 1,1,1-trichloro-2-methyl-2-propanol from chloroform and acetone, a step (b2+b3 or b4) of obtaining methacrylic acid or an ester thereof and hydrogen chloride from 1,1,1-trichloro-2-methyl-2-propanol and water or an alcohol, and a step (c1 or c2) of obtaining chlorine molecule by reacting hydrogen chloride with oxygen molecule.
• US9238612B2
  申请人：——

  公开号：US9238612B2

  公开（公告）日：2016-01-19
• US9617379B2
  申请人：——

  公开号：US9617379B2

  公开（公告）日：2017-04-11