4-甲基-苯磺酸镁盐(2:1) | 36729-49-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 4-甲基-苯磺酸镁盐(2:1)
• 英文名称: Magnesium toluenesulphonate
• 英文别名: magnesium;2-methylbenzenesulfonate
• CAS: 36729-49-4
• 化学式: C14H14MgO6S2
• 分子量: 366.7
• InChiKey: NYZCEWSWSSPEFF-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  1.42
• 重原子数：
  23
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  131
• 氢给体数：
  0
• 氢受体数：
  6

文献信息

• Olefin dimers, derivatives thereof and organoleptic uses thereof
  申请人：INTERNATIONAL FLAVORS & FRAGRANCES INC.

  公开号：EP0042734A2

  公开（公告）日：1981-12-30

  In the augmenting or enhancing of aroma or taste of consumable materials, certain diisoamylene compounds or derivatives are used. Specific novel diisoamylene derivatives are also disclosed, having utility for organoleptic uses.

  在增加或提高消费品的香气或味道时，会用到某些二异亚氨基甲烷化合物或衍生物。此外，还公开了特定的新型二异亚氨基甲酸乙酯衍生物，这些衍生物在感官用途方面具有实用性。
• Bleaching composition
  申请人：INTERNATIONAL FLAVORS & FRAGRANCES INC.

  公开号：EP0347596A2

  公开（公告）日：1989-12-27

  Dimethyl substituted alkyl nitriles according to the generic structure: wherein N represents 0 or 1 have organoleptic uses augmenting or enhancing the aroma of perfume compositions, colognes and perfumed articles including but not limited to bleach compositions, solid or liquid anionic, cationic, nonionic or zwitterionic detergents, perfumed polymers, fabric softener compositions, fabric softener articles, cosmetic powders and hair preparations. Such dimethyl substituted alkyl nitriles may be obtained by reaction of aldehydes defined according to the structure: with hydroxylamine salts having the structure: wherein Y is an anion and P is 1 or 2 to form aldoximes defined according to the structure:

  通用结构的二甲基取代烷基腈： 其中 N 代表 0 或 1 的二甲基取代烷基腈具有感官用途，可增加或提高香水组合物、古龙水和含香物品的香气，包括但不限于漂白剂组合物、固体或液体阴离子、阳离子、非离子或齐聚物洗涤剂、含香聚合物、织物柔软剂组合物、织物柔软剂物品、化妆品粉末和头发制剂。 此类二甲基取代的烷基腈可通过以下结构定义的醛与羟胺盐反应获得： 与具有以下结构的羟胺盐反应，可获得此类二甲基取代的烷基腈： 其中 Y 为阴离子，P 为 1 或 2，形成按结构定义的醛肟：
• 2,4,4-Trisubstituted tetrahydropyranyl esters and organoleptic uses thereof
  申请人：INTERNATIONAL FLAVORS & FRAGRANCES INC.

  公开号：EP0383446A2

  公开（公告）日：1990-08-22

  Described are 2,4,4-trisubstituted tetrahydro pyranyl esters defined according to the structure: wherein R, represents methyl or ethyl and R2 represents C2-C4 straight chain or branched chain alkyl or alkenyl and organoleptic uses thereof in augmenting or enhancing the aroma of perfume compositions, colognes and perfumed articles including, but not limited to bleach compositions, solid or liquid anionic, cationic, nonionic or zwitterionic detergents, perfumed polymers, fabric softener compositions, fabric softener articles, cosmetic powders and hair preparations.

  描述了根据以下结构定义的 2,4,4-三取代四氢吡喃酯： 其中 R 代表甲基或乙基，R2 代表 C2-C4 直链或支链烷基或烯基，其感官用途是增加或提高香水组合物、古龙水和加香物品的香气，包括但不限于漂白剂组合物、固体或液体阴离子、阳离子、非离子或齐聚物洗涤剂、加香聚合物、织物柔软剂组合物、织物柔软剂物品、化妆品粉末和头发制剂。
• 2,2-Dimethyl-1-nitrilo or 2,2-dimethyl-1-hydroxylamino-3-(alkyl phenyl)substituted propanes or 2-methyl-1-nitrilo-or 2-methyl-1-hydroxylamino-3-(methoxyphenyl) propane, organoleptic uses thereof and processes for preparing same
  申请人：INTERNATIONAL FLAVORS & FRAGRANCES INC.

  公开号：EP0440362A1

  公开（公告）日：1991-08-07

  The present invention provides 2,2-dimethyl-1-nitrilo or 2,2-dimethyl-1-hydroxylamino-3-(alkyl phenyl) substituted propanes or 2-methyl-1-nitrilo- or 2-methyl-1-hydroxylamino-3-(methoxyphenyl) propane, and a process of augmenting or enhancing the aroma of a consumable material with a quantity of such a compound or mixture of compounds.

  本发明提供了 2,2-二甲基-1-硝基或 2,2-二甲基-1-羟基氨基-3-（烷基苯基）取代丙烷或 2-甲基-1-硝基或 2-甲基-1-羟基氨基-3-（甲氧基苯基）丙烷，以及用一定量的此类化合物或化合物混合物增加或提高消费品香气的工艺。
• OLEFIN OLIGOMERIZATION CATALYST AND PROCESS FOR THE PREPARATION OF OLEFIN OLIGOMER USING IT
  申请人：NIPPON OIL COMPANY, LTD.

  公开号：EP0758563A1

  公开（公告）日：1997-02-19

  An oligomerization catalyst according to the invention comprises a nickel compound (A); an organophosphoric compound (B); an organoaluminum compound (C); and a compound of the group consisting of carbon-halogen bond-containing compounds, oxoacid and salts thereof, sulfonic acid and derivatives thereof, and compounds of any of the formulae QX4n, QRn, QR'n, QX4lRm, QX4lR'm, QRlR'm, Q1(BR4)p and R''(BR4) wherein Q is an element of the group consisting of Mg, Ti, Zr, B and Sn, Q1 is an element of the group consisting of Li, Na, K, Ca and Zn, X4 is a halogen or hydrogen atom, R is a C1-C12 hydrocarbon group, R' is a C1-C12 oxygen-containing hydrocarbon groiup, R'' is a C1-C20 hydrocarbon group or an ammonium group, n is a valence of Q, l, m is a natural member that satisfied n=l+m, and p is a valence of Q1. This catalyst is useful for the production of alpha-olefinic oligomers.

  根据本发明的低聚催化剂包括镍化合物（A）；有机磷化合物（B）；有机铝化合物（C）；以及由以下物质组成的一组化合物：含碳-卤素键化合物、氧酸及其盐、磺酸及其衍生物，以及式 QX4n、QRn、QR'n、QX4lRm、QX4lR'm、QRlR'm、Q1(BR4)p 和 R''(BR4)中任何一种的化合物 其中 Q 是由镁、钛、锆、硼和锡组成的组中的元素、X4 是卤素或氢原子，R 是 C1-C12 烃基，R'是 C1-C12 含氧烃基，R''是 C1-C20 烃基或铵基，n 是 Q 的化合价，l、m 是满足 n=l+m 的自然数，p 是 Q1 的化合价。这种催化剂可用于生产α-烯烃低聚物。