trans-anti-4-Carbomethoxy-1-decalon | 23595-71-3

• 分子结构分类: 有机化合物
• 英文名称: trans-anti-4-Carbomethoxy-1-decalon
• 英文别名: 1-Naphthalenecarboxylic acid, decahydro-4-oxo-, methyl ester；(+/-)-4-oxo-(4ar,8at)-decahydro-[1c]naphthoic acid methyl ester；(+/-)-4-Oxo-(4ar,8at)-decahydro-[1c]naphthoesaeure-methylester；trans-syn-4-Oxo-1-methoxycarbonyl-decalin
• CAS: 23595-71-3；25920-49-4；91765-34-3；128822-19-5
• 化学式: C₁₂H₁₈O₃
• 分子量: 210.273
• InChiKey: JPFUEZPXKCRLTQ-LPEHRKFASA-N

物化性质

• 熔点：
  89-91 °C
• 沸点：
  308.1±35.0 °C(Predicted)
• 密度：
  1.092±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.94
• 重原子数：
  15.0
• 可旋转键数：
  1.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  43.37
• 氢给体数：
  0.0
• 氢受体数：
  3.0

反应信息

• 作为反应物：
  描述：

  trans-anti-4-Carbomethoxy-1-decalon 在 盐酸 、 sodium azide 、 amalgamated zinc 、 硫酸 作用下， 生成 (+/-)-(4ar,8at)-decahydro-[1c]naphthylamine
  参考文献：
  名称：

  Overexpression of the Arabidopsis thaliana MinD1 gene alters chloroplast size and number in transgenic tobacco plants

  摘要：

  The Arabidopsis thaliana (L.) Heynh. minD gene (AtMinD1) was isolated and constitutively expressed in tobacco (Nicotiana tabacum L.) plants using the CaMV 35S promoter. Confocal and electron-microscopic analysis of the AtMinD1 transgenic tobacco lines revealed that the chloroplasts were abnormally large and fewer in number compared with wild-type tobacco plants. The abnormal chloroplasts were less prevalent in guard cells than in mesophyll cells. Chloroplast and nuclear gene expression was not significantly different in AtMinD1-overexpressing plants relative to wild-type tobacco plants. Chloroplast DNA copy number was not affected, based on the relative level of the rbcL gene in transgenic plants. Transgenic tobacco plants constitutively overexpressing AtMinD1 were completely normal phenotypically with respect to growth and development, and also displayed normal photosynthetic electron transport rates. These results show that the Arabidopsis MinD1 gene also functions in a heterologous system and confirm the role of the MinD protein in regulation of chloroplast division.

  DOI：

  10.1007/s004250100605
• 作为产物：
  描述：

  (+/-)-4a-hydroxy-4-oxo-(4ar,8at)-decahydro-[1c]naphthoic acid-lactone 在 盐酸 、 amalgamated zinc 作用下， 生成 trans-anti-4-Carbomethoxy-1-decalon
  参考文献：
  名称：

  Kutscherow et al., Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1959, p. 682,688; engl. Ausg. S. 652, 657

  摘要：

  DOI：

文献信息

• Stereochemistry of cyclic compounds
  作者：G. M. Segal'、L. P. Rybkina、V. F. Kucherov

  DOI：10.1007/bf00907982

  日期：1962.8
• Nasarow et al., 1956, p. 1215,1217; engl. Ausg. S. 1241, 1243
  作者：Nasarow et al.

  DOI：——

  日期：——