thallium(I) bis(perchlorophenyl)aurate(I) | 671225-85-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: thallium(I) bis(perchlorophenyl)aurate(I)
• CAS: 671225-85-7
• 化学式: C₁₂AuCl₁₀*Tl
• 分子量: 900.012
• InChiKey: JAKPHRBBTMGXSD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  thallium(I) bis(perchlorophenyl)aurate(I) 以 四氢呋喃 为溶剂， 生成
  参考文献：
  名称：

  Long-Chain Ketimine Synthesis in a Gold−Thallium Polymer

  摘要：

  The heteropolynuclear complex [Tl{Au(C6Cl5)(2)}(n) reacts with sterically demanding diamines as tetramethylenediamine (TMDA), 2,2'-(ethylenedioxy)bis(ethylamine) (NOON), or triethylenetetramine (trien) in 1:1 molar ratio in tetrahydrofuran (THF), leading to products of stoichiometry [Tl{Au(C6Cl5)2}(L)] (L = TM-DA (1), NOON (2), or trien (3)) or [Tl-2{Au(C6Cl5)2}2(L)] (L = tfien (4)) when the solvent used is toluene. Addition of acetylacetone to the diamine complexes in 1:1 molar ratio generates [Tl{Au(C6Cl5)(2)}{O=C(CH3)CHC(CH3)NH(CH2)(4)NH2}](n) (5) and in 1:2 molar ratio [Tl{Au(C6Cl5)(2)}(L-x)](n) (L-x= {O=C(CH3)CHC(CH3)NHCH2CH2}(2) (6), {O=C(CH3)CHC(CH3)NHCH2CH2OCH2}(2) (7)). When the molar ratio is 1:2, with the exception of 3, all these complexes display luminescence in the solid state at room temperature and at 77 K. The origin of the luminescence could be assigned to a delocalizated exciton along the heterometallic chain formed by Au center dot center dot center dot Tl interactions. In addition, a red shift is observed when the temperature decreases, which is attributed to the shortening of the Au-Tl distance at lower temperatures. The emissive properties of solutions of 5-7 and [Tl{Au(C6Cl5)(2)}](n) in THF were studied after adding increasing amounts of different metal ions (Zn2+, Cd2+, Hg2+, Pb2+, Al3+, Ni2+, Ag+, Mn2+, Bi3+) and anions (F-, Cl-, Br-, I-, H2PO4-, ClO4-, Bz(-), Ac-, HSO4-, NO3-). Interestingly, an enhancement of the fluorescence emission intensity was observed for the complexes considered only upon addition of Br-, Cl-, and Ac-.

  DOI：

  10.1021/om100188f
• 作为产物：
  描述：

  thallium(I) hexafluorophosphate 、 N-n-Bu4{Au(C6Cl5)2} 以 四氢呋喃 为溶剂， 以65%的产率得到thallium(I) bis(perchlorophenyl)aurate(I)
  参考文献：
  名称：

  {Tl[Au(C₆Cl₅)₂]}_n:  A Vapochromic Complex

  摘要：

  The X-ray structure of (Tl[Au(C(6)Cl(5))(2)])(n), 1, consists of 1-D linear polymer chains parallel to the crystallographic z axis. The crystal structure of 1 has channels that run parallel to these chains with interatom distances in the range 3.231-4.076 A. There are holes in these channels with diameters as large as 10.471 A, which can accommodate a variety of solvents. Complex 1 displays reversible vapochromic emission and absorption spectral behavior when the solid is exposed to a variety of organic vapors such as acetone, acetonitrile, triethylamine, acetylacetone, tetrahydrothiophene, 2-fluoropyridine, tetrahydrofuran, and pyridine. Complex 1 is luminescent at room temperature and at 77 K in the solid state. UV excitation at 495 nm leads to an emission at 531 nm.

  DOI：

  10.1021/ja028734u