1,1-di-2-pyridylethyl methyl ether | 137731-80-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 1,1-di-2-pyridylethyl methyl ether
• 英文别名: 2-(1-methoxy-1-pyridin-2-ylethyl)pyridine
• CAS: 137731-80-7
• 化学式: C₁₃H₁₄N₂O
• 分子量: 214.267
• InChiKey: YPUNEJBYJNZEFX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.4
• 重原子数：
  16
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.23
• 拓扑面积：
  35
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  copper(l) iodide 、 1,1-di-2-pyridylethyl methyl ether 以 乙腈 为溶剂， 生成 {Cu(II)(1,1-di(2-pyridyl)ethyl methyl ether)2}{Cu(I)2I4}
  参考文献：
  名称：

  Copper complexes of 1,1-di(2-pyridyl)ethyl methyl ether: X-ray crystal structures and reactions with dioxygen

  摘要：

  The mixed-valence complexes [Cu(II)L3(1)][Cu2lI4] (L1 = di-2-pyridyl ketone), [Cu(II)(HL2)2][Cu2lI4] [HL2 = 1,1-di(2-pyridyl)ethanol] and [Cu(II)L2(3)][Cu2lI4] [L3 = 1,1-di(2-pyridyl)ethyl methyl ether] have been isolated from the reactions of CuI with the respective ligands. On interactions with dioxygen the last two complexes are oxidised to [Cu(II)2L(2)2I2] and [Cu(II)2L2(3)(OH)2][Cu(I)I3] respectively. The X-ray crystal structures of [Cu(II)L2(3)][Cu(I)2I4] and [Cu(II)2L2(3)(OH)2][Cu(I)I3] are reported.

  DOI：

  10.1039/dt9910002539
• 作为产物：
  描述：

  2-二吡啶基酮 在 sodium hydride 作用下， 以 乙醚 为溶剂， 反应 2.5h， 生成 1,1-di-2-pyridylethyl methyl ether
  参考文献：
  名称：

  Copper complexes of 1,1-di(2-pyridyl)ethyl methyl ether: X-ray crystal structures and reactions with dioxygen

  摘要：

  The mixed-valence complexes [Cu(II)L3(1)][Cu2lI4] (L1 = di-2-pyridyl ketone), [Cu(II)(HL2)2][Cu2lI4] [HL2 = 1,1-di(2-pyridyl)ethanol] and [Cu(II)L2(3)][Cu2lI4] [L3 = 1,1-di(2-pyridyl)ethyl methyl ether] have been isolated from the reactions of CuI with the respective ligands. On interactions with dioxygen the last two complexes are oxidised to [Cu(II)2L(2)2I2] and [Cu(II)2L2(3)(OH)2][Cu(I)I3] respectively. The X-ray crystal structures of [Cu(II)L2(3)][Cu(I)2I4] and [Cu(II)2L2(3)(OH)2][Cu(I)I3] are reported.

  DOI：

  10.1039/dt9910002539