| 200349-23-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 200349-23-1
• 化学式: C₂₇H₂₃BrN₇RuS*ClO₄
• 分子量: 758.017
• InChiKey: IIFZGOLLHVHWAA-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  顺-双(2,2-二吡啶)二氯化钌(II) 水合物 、 lithium perchlorate 、 4-(4-溴苯基)-3-氨基硫脲 在 NH₄OH 作用下， 以 甲醇 、 水 为溶剂， 生成
  参考文献：
  名称：

  Synthesis and characterization of bis(2,2′-bipyridine) ruthenium complexes containing thiosemicarbazide ligands: unique redox series

  摘要：

  Two series of heterochelates of ruthenium(II) containing two bipyridyl molecules and a bidentate chelating sulfur-nitrogen donor ligand in the form of Lt-aryl substituted thiosemicarbazides have been synthesized and characterized. The first series of complexes are dicationic in which the ring substituted 4-aryl thiosemicarbazides (N-S) are chelated in the keto form through the hydrazinic nitrogen and the thione sulfur atom. They are of the [Ru(bpy)(2)NS](+2) type. The second series have the general formula [Ru(bpy)(2)NS](+1) in which the thiosemicarbazide moiety remains chelated to the Ru-II centre through the hydrazinic nitrogen and the deprotonated thiolato S-atom. All the complexes have been characterized by elemental analysis, UV-vis, IR and EPR spectroscopy. The complexes were found to constitute a three membered redox series which were investigated by cyclic voltammetry. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0277-5387(97)00214-3