[Mn(2-pyridylmethyl-2-hydroxyphenylimine(1-))2] * H2O | 487016-27-3

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: [Mn(2-pyridylmethyl-2-hydroxyphenylimine(1-))2] * H2O
• CAS: 487016-27-3
• 化学式: C₂₄H₁₈MnN₄O₂*H₂O
• 分子量: 467.386
• InChiKey: KFSFJKYGBZDNJF-YOMCRPSHSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Mn(2-pyridylmethyl-2-hydroxyphenylimine(1-))2] * H2O 、 四苯硼钠 、 manganese (II) acetate tetrahydrate 以 甲醇 、 乙腈 为溶剂， 以86%的产率得到[Mn4(2-pyridylmethyl-2-hydroxyphenylimine(1-))6](BPh4)2
  参考文献：
  名称：

  A Tetranuclear Manganese Cluster with a Star-Shaped Mn4O6 Core Motif: Directed Synthesis using a Mononuclear Precursor Complex

  摘要：

  The tetranuclear manganese(II) complex [Mn-4(PPi)(6)](BPh4)(2) (2) (Hppi = 2-pyridylmethyl-2-hydroxyphenylimine) is prepared by using the precursor complex [Mn(PPi)(2)]-H2O (1). Based on UV/Vis- and IR-spectroscopy data in combination with mass spectrometry it has been concluded that I is a mononuclear neutral Mn-II complex, in which two ppi ligands chelate the manganese atom. Compound 2 crystallizes in the tri-clinic space group P (1) over bar (no. 2), with a = 17.500(3), b = 17.955(4), c = 19.101(4) Angstrom, alpha = 113.79(3)degrees, beta = 111.33(3)degrees, gamma = 93.91(3)degrees, V = 4950(2) Angstrom(3) and Z = 2. In the tetranuclear [Mn-4(PPi)(6)](2+) compplex cation Mn(l), Mn(2), and Mn(3) are equivalently coordinated by two deprotonated Hppi ligands leading to a N4O2 donor set. The environment of the central Mn(4) is formed by coordination of three [Mn(PPi)(2)] fragments resulting in a phenoxo bridged star-shaped Mn4O6 core motif. The average distance of directly adjacent manganese ions is 3.310 Angstrom, whereas the average distance of Mn(1), Mn(2), and Mn(3) among each other is 5.732 Angstrom.

  DOI：

  10.1002/1521-3749(200211)628:11<2458::aid-zaac2458>3.0.co;2-6
• 作为产物：
  描述：

  2-[(2-pyridinylmethylene)amino]phenol 、 水 、 manganous acetylacetonate 以 丙酮 为溶剂， 以92%的产率得到[Mn(2-pyridylmethyl-2-hydroxyphenylimine(1-))2] * H2O
  参考文献：
  名称：

  A Tetranuclear Manganese Cluster with a Star-Shaped Mn4O6 Core Motif: Directed Synthesis using a Mononuclear Precursor Complex

  摘要：

  The tetranuclear manganese(II) complex [Mn-4(PPi)(6)](BPh4)(2) (2) (Hppi = 2-pyridylmethyl-2-hydroxyphenylimine) is prepared by using the precursor complex [Mn(PPi)(2)]-H2O (1). Based on UV/Vis- and IR-spectroscopy data in combination with mass spectrometry it has been concluded that I is a mononuclear neutral Mn-II complex, in which two ppi ligands chelate the manganese atom. Compound 2 crystallizes in the tri-clinic space group P (1) over bar (no. 2), with a = 17.500(3), b = 17.955(4), c = 19.101(4) Angstrom, alpha = 113.79(3)degrees, beta = 111.33(3)degrees, gamma = 93.91(3)degrees, V = 4950(2) Angstrom(3) and Z = 2. In the tetranuclear [Mn-4(PPi)(6)](2+) compplex cation Mn(l), Mn(2), and Mn(3) are equivalently coordinated by two deprotonated Hppi ligands leading to a N4O2 donor set. The environment of the central Mn(4) is formed by coordination of three [Mn(PPi)(2)] fragments resulting in a phenoxo bridged star-shaped Mn4O6 core motif. The average distance of directly adjacent manganese ions is 3.310 Angstrom, whereas the average distance of Mn(1), Mn(2), and Mn(3) among each other is 5.732 Angstrom.

  DOI：

  10.1002/1521-3749(200211)628:11<2458::aid-zaac2458>3.0.co;2-6