(silver)(saccharinate)(N,N-diethylethylenediamine) | 1229034-61-0

• 分子结构分类: 有机化合物 - 苯类化合物
• 英文名称: (silver)(saccharinate)(N,N-diethylethylenediamine)
• CAS: 1229034-61-0
• 化学式: C₁₃H₂₀AgN₃O₃S
• 分子量: 406.254
• InChiKey: FDVNHUGGELMCRJ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (silver)(saccharinate)(N,N-diethylethylenediamine) 以 neat (no solvent, solid phase) 为溶剂， 生成 银
  参考文献：
  名称：

  Syntheses, thermal analyses, crystal structures and antimicrobial properties of silver(I)-saccharinate complexes with diverse diamine ligands

  摘要：

  Five new silver(I)-saccharinate complexes [Ag-2(sac)(2)(tmen)(2)] (1), [Ag-2(sac)(2)(deten)(2)] (2), [Ag-2(sac)(2)(dmen)(2)] (3), [Ag(sac)(N,N-eten)] (4), and [Ag(sac)(dmpen)](n) (5); (sac = saccharinate, tmen = N,N,N',N'-tetramethylethylenediamine, deten = N,N'-diethylethylenediamine, dmen = N,N'-dimethylethylenediamine, N,N-eten = N,N-diethylethylenediamine and dmpen = 1,3-diamino-2,2-dimethylpropan) have been synthesized and characterized by elemental analyses, IR, thermal analyses, single crystal X-ray diffraction and antimicrobial activities. The crystallographic analyses show that all the complexes crystallize in monoclinic space group P2(1)/c. In 1, the sac ligand acts as a bridge to connect the silver centres through its imino N and carbonyl O atoms forming an eight-membered bimetallic ring in a chair conformation. Complex 2 has also a dimeric structure in which the monomeric [Ag(sac)(deten)] units are linked by Ag center dot center dot center dot Ag interactions. In 3, saccharinate ligand acts as a bridging bidentate ligand between two silver(I) centres through sulfonyl group and imino N atom, forming an alternating polymeric chain through the direction [0 1 0]. In 4, the inter-molecular N-H center dot center dot center dot O hydrogen bonds form one-dimensional polymeric chains through the a axis, and these linear chains are inter-connected to each other by N-H center dot center dot center dot O hydrogen bonds, which produce a chain of edge-fused R-4(4)(16) and R-2(2)(12) rings along [1 0 0]. Complex 5 is a coordination polymer in which the monomeric [Ag(dmpen)(sac)](n) units are linked by Ag center dot center dot center dot Ag interactions, and the dmpen ligand acts as a bridge between the silver(I) ions, forming a two-dimensional network parallel to the (1 0 0) plane. (C) 2010 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2010.02.013
• 作为产物：
  描述：

  silver saccharin 、 N,N-二乙基乙二胺 以 水 为溶剂， 生成 (silver)(saccharinate)(N,N-diethylethylenediamine)
  参考文献：
  名称：

  Syntheses, thermal analyses, crystal structures and antimicrobial properties of silver(I)-saccharinate complexes with diverse diamine ligands

  摘要：

  Five new silver(I)-saccharinate complexes [Ag-2(sac)(2)(tmen)(2)] (1), [Ag-2(sac)(2)(deten)(2)] (2), [Ag-2(sac)(2)(dmen)(2)] (3), [Ag(sac)(N,N-eten)] (4), and [Ag(sac)(dmpen)](n) (5); (sac = saccharinate, tmen = N,N,N',N'-tetramethylethylenediamine, deten = N,N'-diethylethylenediamine, dmen = N,N'-dimethylethylenediamine, N,N-eten = N,N-diethylethylenediamine and dmpen = 1,3-diamino-2,2-dimethylpropan) have been synthesized and characterized by elemental analyses, IR, thermal analyses, single crystal X-ray diffraction and antimicrobial activities. The crystallographic analyses show that all the complexes crystallize in monoclinic space group P2(1)/c. In 1, the sac ligand acts as a bridge to connect the silver centres through its imino N and carbonyl O atoms forming an eight-membered bimetallic ring in a chair conformation. Complex 2 has also a dimeric structure in which the monomeric [Ag(sac)(deten)] units are linked by Ag center dot center dot center dot Ag interactions. In 3, saccharinate ligand acts as a bridging bidentate ligand between two silver(I) centres through sulfonyl group and imino N atom, forming an alternating polymeric chain through the direction [0 1 0]. In 4, the inter-molecular N-H center dot center dot center dot O hydrogen bonds form one-dimensional polymeric chains through the a axis, and these linear chains are inter-connected to each other by N-H center dot center dot center dot O hydrogen bonds, which produce a chain of edge-fused R-4(4)(16) and R-2(2)(12) rings along [1 0 0]. Complex 5 is a coordination polymer in which the monomeric [Ag(dmpen)(sac)](n) units are linked by Ag center dot center dot center dot Ag interactions, and the dmpen ligand acts as a bridge between the silver(I) ions, forming a two-dimensional network parallel to the (1 0 0) plane. (C) 2010 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2010.02.013