3,5-dichloro-4-hydroxybenzyl methyl ether | 79817-03-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3,5-dichloro-4-hydroxybenzyl methyl ether
• 英文别名: 2,6-dichloro-4-methoxymethyl-phenol；Methyl-(3.5-dichlor-4-hydroxy-benzyl)-aether；2,6-Dichlor-4-methoxymethyl-phenol；3.5-Dichlor-4-hydroxy-α-methoxy-toluol；2,6-Dichloro-4-(methoxymethyl)phenol
• CAS: 79817-03-1
• 化学式: C₈H₈Cl₂O₂
• 分子量: 207.056
• InChiKey: HJWUGZSOJFHVCX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  12
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  29.5
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  二甲基硫代磷酰氯 、 3,5-dichloro-4-hydroxybenzyl methyl ether 、 potassium carbonate 、 氯化亚铜 以67%的产率得到
  参考文献：
  名称：

  SASAKI, MITSURU;OOISHI, TADASHI;KATO, TOSHIRO;TAKAYAMA, CHIYOZO;MUKAI, KU+, J. PESTIC. SCI., 1984, 9, N 4, 737-744

  摘要：

  DOI：
• 作为产物：
  描述：

  4-(chloromethyl)-2,6-dichlorophenol 在 盐酸 作用下， 以 乙醚 为溶剂， 反应 7.0h， 生成 3,5-dichloro-4-hydroxybenzyl methyl ether
  参考文献：
  名称：

  Regioselective alkylation of anthrahydroquinone and anthrone in water with quinonemethides and other alkylating agents

  摘要：

  DOI：

  10.1021/jo00340a006

文献信息

• ILO principles concerning collective bargaining
  作者：Bernard GERNIGON、Alberto ODERO、Horacio GUIDO

  DOI：10.1111/j.1564-913x.2000.tb00401.x

  日期：2000.3

  The major changes now occurring worldwide are also affecting collective bargaining: the coverage of collective agreements is shrinking, and there are growing numbers of enterprise-based agreements and settlements concerning the public sector in many countries. Nevertheless, the adaptability of the international principles involved ensures their enduring validity. The authors describe the principles expressed in the ILO's Conventions and Recommendations and by the bodies charged with supervising compliance therewith. Finally, they give a general view of collective bargaining as a fundamental right and of the degree to which it is applied.
• Phenolic oxidation of o,o′-dihalogenated phenols
  作者：Masakatsu Takahashi、Hironori Konishi、Satoshi Iida、Kensuke Nakamura、Shosuke Yamamura、Shigeru Nishiyama

  DOI：10.1016/s0040-4020(99)00217-3

  日期：1999.4

  A detailed inspection of phenolic oxidation products derived from the o,o'-dihalogenated cresol derivatives (1a - 1e) indicated that the bromo and chloro substituents promoted the oxidation leading to the corresponding diaryl ethers, whereas the iodo derivatives provided the diaryls. Selective reduction of 6d and its tyrosine derivative afforded the corresponding diaryl ethers carrying two chlorine atoms (14, 15). interpretation of the selectivity of the phenolic oxidation was attempted by employing theoretical calculations. (C) 1999 Elsevier Science Ltd. All rights reserved.
• DIMMEL, D. R.;SHEPART, D., J. ORG. CHEM., 1982, 47, N 1, 22-29
  作者：DIMMEL, D. R.、SHEPART, D.

  DOI：——

  日期：——
• Regioselective alkylation of anthrahydroquinone and anthrone in water with quinonemethides and other alkylating agents
  作者：Donald R. Dimmel、Donaline Shepard

  DOI：10.1021/jo00340a006

  日期：1982.1
• SASAKI, MITSURU;OOISHI, TADASHI;KATO, TOSHIRO;TAKAYAMA, CHIYOZO;MUKAI, KU+, J. PESTIC. SCI., 1984, 9, N 4, 737-744
  作者：SASAKI, MITSURU、OOISHI, TADASHI、KATO, TOSHIRO、TAKAYAMA, CHIYOZO、MUKAI, KU+

  DOI：——

  日期：——