bis(N-(2-hydroxyphenyl)-salicylideniminato)vanadium(IV) | 143228-03-9

• 分子结构分类: 有机化合物 - 苯类化合物
• 英文名称: bis(N-(2-hydroxyphenyl)-salicylideniminato)vanadium(IV)
• 英文别名: bis[salicylaldehyde-2-hydroxyanilato(2-)]vanadium(IV)
• CAS: 143228-03-9
• 化学式: C₂₆H₁₈N₂O₄V
• 分子量: 473.381
• InChiKey: XSOWLPYJSOFXBO-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  sodium hydrogen sulfide 、 bis(N-(2-hydroxyphenyl)-salicylideniminato)vanadium(IV) 以 乙醇 为溶剂， 生成
  参考文献：
  名称：

  Synthesis, spectra and electrochemistry of non-oxovanadium(IV) bischelates of tridentate schiff base ligands. Magnetism of bis[N-(2-hydroxyphenyl)-5-methylsalicylideniminato]vanadium(IV)

  摘要：

  Three non-oxo bis-chelated complexes of vanadium(IV) with the Schiff base N-(2-hydroxyphenyl)salicylideneamine and its substituted derivatives were synthesized and characterized by elemental analysis, conductivity measurements, magnetic and spectral data. Cyclic voltammetric experiments in DMF solution at a glassy-carbon working electrode reveal nearly reversible V(IV)/V(III) (-0.07 to -0.12 V vs S.C.E.) and V(III)/V(II) (-1.77 to -1.80 V vs S.C.E.). The corresponding vanadium(III) species has been generated by chemical/electrochemical reduction of the vanadium(IV) complexes and characterized by their absorption spectra and cyclic voltammetry.

  DOI：

  10.1016/s0277-5387(00)80178-3
• 作为产物：
  描述：

  bis(acetylacetonate)oxovanadium 、 2-羟基缩苯胺 以 甲醇 为溶剂， 生成 bis(N-(2-hydroxyphenyl)-salicylideniminato)vanadium(IV)
  参考文献：
  名称：

  Synthesis, spectra and electrochemistry of non-oxovanadium(IV) bischelates of tridentate schiff base ligands. Magnetism of bis[N-(2-hydroxyphenyl)-5-methylsalicylideniminato]vanadium(IV)

  摘要：

  Three non-oxo bis-chelated complexes of vanadium(IV) with the Schiff base N-(2-hydroxyphenyl)salicylideneamine and its substituted derivatives were synthesized and characterized by elemental analysis, conductivity measurements, magnetic and spectral data. Cyclic voltammetric experiments in DMF solution at a glassy-carbon working electrode reveal nearly reversible V(IV)/V(III) (-0.07 to -0.12 V vs S.C.E.) and V(III)/V(II) (-1.77 to -1.80 V vs S.C.E.). The corresponding vanadium(III) species has been generated by chemical/electrochemical reduction of the vanadium(IV) complexes and characterized by their absorption spectra and cyclic voltammetry.

  DOI：

  10.1016/s0277-5387(00)80178-3

文献信息

• Ludwig, E.; Hefele, H.; Uhlemann, E., Zeitschrift fur Anorganische und Allgemeine Chemie
  作者：Ludwig, E.、Hefele, H.、Uhlemann, E.、Weller, F.、Klaeui, W.

  DOI：——

  日期：——
• Hefele, H.; Ludwig, E.; Uhlemann, E., Zeitschrift fur Anorganische und Allgemeine Chemie
  作者：Hefele, H.、Ludwig, E.、Uhlemann, E.、Weller, F.

  DOI：——

  日期：——