| 219135-93-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 219135-93-0
• 化学式: C₁₄H₁₀Mo₂O₄S₄
• 分子量: 562.375
• InChiKey: WSNMUNIWQOMERW-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  吡啶 、 以 二氯甲烷 为溶剂， 以26%的产率得到Mo₂O₂S₂(OSCC₆H₅)2(C₅H₅N)2
  参考文献：
  名称：

  New dinuclear thiobenzoato complexes of molybdenum(V) containing Mo2O2S2 core. X-ray crystal structures of [Mo2O2S2(OSCC6H5)2(py)2] and [Mo2O2S2(OSCC6H5)2(γ-pic)2]·2H2O

  摘要：

  The [Mo2O2S2(OSCC6H5)(2)] (1) has been prepared either by the reaction of [Mo2O3(C5H7O2)(4)] or of [Mo4Cl2O6(O2CCH3)(6)].(CH3CO)(2)O with thiobenzoic acid. The product was then used to prepare two complexes of the general formula [Mo2O2S2(OSCC6H5)(2)L-2] (where L = pyridine (2) or gamma-picoline (3)). All complexes were characterized by elemental analyses, IR spectra and magnetic measurements. The structures of (2) and (3) were proved by X-ray structure analysis. Both complexes are dinuclear containing Mo2O2S2 core with two Mo atoms linked by a Mo-Mo single bond. The Mo atoms are octahedrally coordinated by ore-oxygen, two bridging sulfido-sulfurs, one pyridine (or gamma-picoline)-nitrogen and thiobenzoato-sulfur and thiobenzoato-oxygen atoms. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(98)00111-9
• 作为产物：
  描述：

  硫代苯甲酸 、 2MoO⁽³⁺⁾*O^(2-)*4(CH₃C(O))2CH^(1-)=Mo₂O₃((CH₃C(O))2CH)4 以 二氯甲烷 为溶剂， 以57%的产率得到
  参考文献：
  名称：

  New dinuclear thiobenzoato complexes of molybdenum(V) containing Mo2O2S2 core. X-ray crystal structures of [Mo2O2S2(OSCC6H5)2(py)2] and [Mo2O2S2(OSCC6H5)2(γ-pic)2]·2H2O

  摘要：

  The [Mo2O2S2(OSCC6H5)(2)] (1) has been prepared either by the reaction of [Mo2O3(C5H7O2)(4)] or of [Mo4Cl2O6(O2CCH3)(6)].(CH3CO)(2)O with thiobenzoic acid. The product was then used to prepare two complexes of the general formula [Mo2O2S2(OSCC6H5)(2)L-2] (where L = pyridine (2) or gamma-picoline (3)). All complexes were characterized by elemental analyses, IR spectra and magnetic measurements. The structures of (2) and (3) were proved by X-ray structure analysis. Both complexes are dinuclear containing Mo2O2S2 core with two Mo atoms linked by a Mo-Mo single bond. The Mo atoms are octahedrally coordinated by ore-oxygen, two bridging sulfido-sulfurs, one pyridine (or gamma-picoline)-nitrogen and thiobenzoato-sulfur and thiobenzoato-oxygen atoms. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(98)00111-9