2-Benzyl-5-methyl-phenol | 30091-04-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-Benzyl-5-methyl-phenol
• 英文别名: 3-Hydroxy-1-methyl-4-benzyl-benzol；2-Benzyl-5-methylphenol
• CAS: 30091-04-4
• 化学式: C₁₄H₁₄O
• 分子量: 198.265
• InChiKey: GFKNCXXAEJJPNC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  15
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  2-Benzyl-5-methyl-phenol 在 乙醇 、 sodium ethanolate 、 phosphorus pentoxide 作用下， 生成 2-(trans-2-benzo[1,3]dioxol-5-yl-vinyl)-8-benzyl-5-methyl-chromen-4-one
  参考文献：
  名称：

  Usgaonkar et al., Journal of the Indian Chemical Society, 1953, vol. 30, p. 765,768

  摘要：

  DOI：
• 作为产物：
  描述：

  2-羟基-4-甲基苯甲酮 在 盐酸 、 amalgamated zinc 作用下， 生成 2-Benzyl-5-methyl-phenol
  参考文献：
  名称：

  Usgaonkar et al., Journal of the Indian Chemical Society, 1953, vol. 30, p. 765,768

  摘要：

  DOI：

文献信息

• New mesoporous silicotitaniumphosphate and its application in acid catalysis and adsorption of As(III/V), Cd(II) and Hg(II)
  作者：Manidipa Paul、Nabanita Pal、M. Ali、Asim Bhaumik

  DOI：10.1016/j.molcata.2010.07.001

  日期：2010.9

  A new mesoporous silicotitaniumphosphate material has been synthesized by using a non-conventional phosphorous source trimethyl phosphite with the aid of Pluronic F127 as structure directing agent (SDA). The mesopores are generated due to the slow hydrolysis of the reactant materials in the presence of supramolecular-assembly of non-ionic surfactant under the evaporation induced self-assembly (EISA) process. The material has been characterized by powder XRD, N-2 sorption, TEM, SEM-EDS, TG-DTA, FT-IR, XPS, Si-29, P-31 MAS NMR and UV-vis spectroscopic techniques. This new mesoporous material has considerably high BET surface area (379 m(2) g(-1)) and narrow pore size distribution with a peak pore width of 5.4 nm. The material showed good catalytic activity in the liquid phase Friedel-Crafts benzylation reaction suggesting strong acidity on its surface. It can also be used as good adsorbent for the removal of toxic metal ions As(III/V), Cd(II) and Hg(II) from the contaminated water. (C) 2010 Elsevier B.V. All rights reserved.
• ACTION OF AROMATIC ALCOHOLS ON AROMATIC COMPOUNDS IN THE PRESENCE OF ALUMINUM CHLORIDE. VIII. BENZYLATION OF META-CRESOL
  作者：Ralph C. Huston、Alva L. Houk

  DOI：10.1021/ja01343a037

  日期：1932.4
• ISMAILOV N.; ABDURASULEVA A. R., IZV. VUZOV. XIMIYA I XIM. TEXNOL., 1979, 22, HO 2, 243-244
  作者：ISMAILOV N.、 ABDURASULEVA A. R.

  DOI：——

  日期：——
• KOROBKOV, V. YU.;GRIGOREVA, E. N.;BYKOV, V. I.;KALECHITS, I. V., XIMIYA TVERD. TOPLIVA,(1988) N 6, S. 91-95
  作者：KOROBKOV, V. YU.、GRIGOREVA, E. N.、BYKOV, V. I.、KALECHITS, I. V.

  DOI：——

  日期：——
• Usgaonkar et al., Journal of the Indian Chemical Society, 1953, vol. 30, p. 765,768
  作者：Usgaonkar et al.

  DOI：——

  日期：——