Phenyl-fluor-silan | 7592-21-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Phenyl-fluor-silan
• 英文别名: Fluoro(phenyl)silane；fluoro(phenyl)silane
• CAS: 7592-21-4
• 化学式: C₆H₇FSi
• 分子量: 126.205
• InChiKey: PWSZPEBVDGOKQL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.37
• 重原子数：
  8
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  Phenyl-fluor-silan 在 copper(l) iodide 、 copper dichloride 作用下， 以 乙醚 为溶剂， 反应 58.0h， 以61%的产率得到Chloro-fluoro-phenyl-silane
  参考文献：
  名称：

  Selective synthesis of halosilanes from hydrosilanes and utilization for organic synthesis

  摘要：

  Selective synthesis of halosilanes has been examined. Various types of halosilanes and halohydrosilanes, such as R3SiX, R2SiHX, R2SiX2, RSiH2X, RSiHX2 (X = Cl, Br, F), were obtained by the reactions of the corresponding hydrosilanes with Cu(II)-based reagents selectively in high yields. This method could be also applied to the synthesis of chlorofluorosilanes and chlorohydrogermanes. On the other hand, iodo- and bromosilanes and germanes were obtained by Pd- or Ni-catalyzed hydride-halogen exchange reactions of hydrosilanes with alkyl or allyl halides. Their synthetic applications have been demonstrated by using iodo-and bromosilanes and chlorofluorosilanes. (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(03)00254-7
• 作为产物：
  描述：

  氯苯基硅烷 在 1-{2-[dibutyl(fluoro)stannanyl]phenyl}-dimethylmethananine 作用下， 以 甲苯 为溶剂， 反应 24.0h， 生成 Phenyl-fluor-silan
  参考文献：
  名称：

  的结构Ç，Ñ -chelated Ñ丁基锡（IV）的氟化物以及它们作为氟化一些氯硅烷，氯膦和金属卤化物的使用剂

  摘要：

  {2-[（（CH 3）2 NCH 2 ] C 6 H 4 } n Bu 2 SnF ）的固态结构中的锡原子与赤道碳原子和轴向氟和氮原子配位为5。{2-[（CH 3）2 NCH 2 ] C 6 H 4 } n BuSnCl 2的氟化通过NMR方法描述。还报道了氟化各种氯硅烷，氯膦和金属卤化物的成功尝试。

  DOI：

  10.1016/j.jfluchem.2007.07.001

文献信息

• POCN Ni(<scp>ii</scp>) pincer complexes: synthesis, characterization and evaluation of catalytic hydrosilylation and hydroboration activities
  作者：Kristina A. Gudun、Medet Segizbayev、Assyl Adamov、Philipp N. Plessow、Konstantin A. Lyssenko、Mannix P. Balanay、Andrey Y. Khalimon

  DOI：10.1039/c8dt04854a

  日期：——

  reactions with HBPin, efficient and mild hydroboration of a variety of carbonyl compounds, including highly chemoselective hydroboration of benzaldehyde in the presence of other common potent reductive functional groups, such as alkenes, alkynes, esters, amides, nitriles, nitro compounds and even ketones, and the first example of base metal catalyzed hydroboration of amides, including mild direct hydroborative

  一系列亚氨基次膦酸酯POCN钳制Ni（II）配合物（POCN）NiMe和（POCN）NiL n（BX 4）（L = CH 3 CN，n = 0，1; X = F，Ph，C 6 F 5）已开发出用于烯烃，醛和酮的催化氢化硅烷化和羰基化合物的氢硼化反应。（POCN）NiMe和（POCN）Ni（BF 4）与PhSiH 3和HBPin的化学计量反应表明催化反应通过氢化物中间体（POCN）NiH。关于与HBPin的反应，对各种羰基化合物进行了有效而温和的硼氢化，包括在存在其他常见的强还原性官能团（例如烯烃，炔烃，酯，酰胺，腈，硝基化合物和（POCN）NiMe证明了贱金属催化酰胺加氢硼化的第一个实例，包括将伯酰胺和仲酰胺轻度直接硼氢化还原成硼化胺。
• Selective synthesis of halosilanes from hydrosilanes and utilization for organic synthesis
  作者：Atsutaka Kunai、Joji Ohshita

  DOI：10.1016/s0022-328x(03)00254-7

  日期：2003.11

  Selective synthesis of halosilanes has been examined. Various types of halosilanes and halohydrosilanes, such as R3SiX, R2SiHX, R2SiX2, RSiH2X, RSiHX2 (X = Cl, Br, F), were obtained by the reactions of the corresponding hydrosilanes with Cu(II)-based reagents selectively in high yields. This method could be also applied to the synthesis of chlorofluorosilanes and chlorohydrogermanes. On the other hand, iodo- and bromosilanes and germanes were obtained by Pd- or Ni-catalyzed hydride-halogen exchange reactions of hydrosilanes with alkyl or allyl halides. Their synthetic applications have been demonstrated by using iodo-and bromosilanes and chlorofluorosilanes. (C) 2003 Elsevier Science B.V. All rights reserved.
• Structure of C, N-chelated nButyltin(IV) fluorides and their use as fluorinating agents of some chlorosilanes, chlorophosphine and metal halides
  作者：Petr Švec、Petr Novák、Milan Nádvorník、Zdeňka Padělková、Ivana Císařová、Lenka Kolářová、Aleš Růžička、Jaroslav Holeček

  DOI：10.1016/j.jfluchem.2007.07.001

  日期：2007.11

  The tin atom in the solid-state structure of 2-[(CH3)2NCH2]C6H4}nBu2SnF is five coordinated with carbon atoms in equatorial and fluorine and nitrogen atoms in axial positions. The fluorination of 2-[(CH3)2NCH2]C6H4}nBuSnCl2 is described by NMR methods. The successful attempts to fluorinate various chlorosilanes, chlorophosphine and metal halides are also reported.

  2-[（（CH 3）2 NCH 2 ] C 6 H 4 } n Bu 2 SnF ）的固态结构中的锡原子与赤道碳原子和轴向氟和氮原子配位为5。2-[（CH 3）2 NCH 2 ] C 6 H 4 } n BuSnCl 2的氟化通过NMR方法描述。还报道了氟化各种氯硅烷，氯膦和金属卤化物的成功尝试。