aluminum;carbon monoxide;N-[2-dimethylphosphanylethyl(dimethyl)-λ5-phosphanylidene]phosphanyl-N-propan-2-ylpropan-2-amine;molybdenum(2+);1,2,3,4,5-pentamethylcyclopenta-1,3-diene;tetrachloride | 377779-37-8

• 分子结构分类: 有机化合物
• 英文名称: aluminum;carbon monoxide;N-[2-dimethylphosphanylethyl(dimethyl)-λ5-phosphanylidene]phosphanyl-N-propan-2-ylpropan-2-amine;molybdenum(2+);1,2,3,4,5-pentamethylcyclopenta-1,3-diene;tetrachloride
• CAS: 377779-37-8
• 化学式: AlCl₄*C₂₄H₄₅MoNO₂P₃
• 分子量: 737.282
• InChiKey: GTCKXZYATKRHKP-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  -4.59
• 重原子数：
  36
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  5.2
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  1,2-双(二甲基瞵)乙烷 、 Cp*Mo(CO)3(η1-PNiPr2)AlCl4 以 not given 为溶剂， 生成 aluminum;carbon monoxide;N-[2-dimethylphosphanylethyl(dimethyl)-λ5-phosphanylidene]phosphanyl-N-propan-2-ylpropan-2-amine;molybdenum(2+);1,2,3,4,5-pentamethylcyclopenta-1,3-diene;tetrachloride
  参考文献：
  名称：

  Reactivity of Electrophilic Terminal Phosphinidene Complexes:  P−P Bond Forming Reactions with Phosphines and Diphosphines

  摘要：

  Reaction of the electrophilic phosphinidene Complex [CP*Mo(CO)(3){(PNPr2)-Pr-i}][AlCl4] with triethylphosphine results in reversible coordination of the phosphine to the phosphinidene phosphorus atom followed by carbonyl displacement at the metal. Phosphine-coordinated phosphinidene complexes with P-P bonds can be isolated by using diphosphines which coordinate first to the phosphinidene and then chelate to the phosphinidene and metal atoms.

  DOI：

  10.1021/om010640q