[(o-(i-Pr)2PC6H4)3In] | 1267636-27-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [(o-(i-Pr)2PC6H4)3In]
• CAS: 1267636-27-0
• 化学式: C₃₆H₅₄InP₃
• 分子量: 694.566
• InChiKey: LSTOBMZKSYANTO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.85
• 重原子数：
  40
• 可旋转键数：
  9
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  bis(tri-tert-butylphosphine)palladium(0) 、 [(o-(i-Pr)2PC6H4)3In] 以 甲苯 为溶剂， 生成 [Pd((o-(i-Pr)2PC6H4)3In)]
  参考文献：
  名称：

  Original Transition Metal→Indium Interactions upon Coordination of a Triphosphine−Indane

  摘要：

  The triphosphine-indane TPI([o-i-Pr2P(C6H4)](3)In) has been prepared and found to react with [Pd(P-t-Bu-3)(2)] and [AuCl(SMe2)]. According to X-ray diffraction analyses and DFT calculations, the ensuing complexes both display original donor acceptor M In interactions, although of markedly different nature and magnitude.

  DOI：

  10.1021/om1011769
• 作为产物：
  描述：

  (o-lithiophenyl)diisopropylphosphine 、 氯化铟 以 甲苯 为溶剂， 生成 [(o-(i-Pr)2PC6H4)3In]
  参考文献：
  名称：

  Original Transition Metal→Indium Interactions upon Coordination of a Triphosphine−Indane

  摘要：

  The triphosphine-indane TPI([o-i-Pr2P(C6H4)](3)In) has been prepared and found to react with [Pd(P-t-Bu-3)(2)] and [AuCl(SMe2)]. According to X-ray diffraction analyses and DFT calculations, the ensuing complexes both display original donor acceptor M In interactions, although of markedly different nature and magnitude.

  DOI：

  10.1021/om1011769

文献信息

• Original Transition Metal→Indium Interactions upon Coordination of a Triphosphine−Indane
  作者：Eric J. Derrah、Marie Sircoglou、Maxime Mercy、Sonia Ladeira、Ghenwa Bouhadir、Karinne Miqueu、Laurent Maron、Didier Bourissou

  DOI：10.1021/om1011769

  日期：2011.2.28

  The triphosphine-indane TPI([o-i-Pr2P(C6H4)](3)In) has been prepared and found to react with [Pd(P-t-Bu-3)(2)] and [AuCl(SMe2)]. According to X-ray diffraction analyses and DFT calculations, the ensuing complexes both display original donor acceptor M In interactions, although of markedly different nature and magnitude.