p-Methoxy-propiophenon-hydrazon | 32770-68-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: p-Methoxy-propiophenon-hydrazon
• 英文别名: 1-(4-methoxy-phenyl)-propan-1-one-hydrazone；1-(4-Methoxy-phenyl)-propan-1-on-hydrazon；1-(4-Methoxyphenyl)propylidenehydrazine
• CAS: 32770-68-6
• 化学式: C₁₀H₁₄N₂O
• 分子量: 178.234
• InChiKey: DNEWMMKYBQHJJO-UHFFFAOYSA-N

物化性质

• 沸点：
  301.2±44.0 °C(Predicted)
• 密度：
  1.04±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2
• 重原子数：
  13
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.3
• 拓扑面积：
  47.6
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  p-Methoxy-propiophenon-hydrazon 170.0 ℃ 、399.97 Pa 条件下， 生成 bis-[1-(4-methoxy-phenyl)-propylidene]-hydrazine
  参考文献：
  名称：

  Linnell; Sharma, Quarterly Journal of Pharmacy and Pharmacology, 1939, vol. 12, p. 263,267

  摘要：

  DOI：
• 作为产物：
  描述：

  对甲氧基苯丙酮 在 一水合肼 作用下， 以 乙醇 为溶剂， 反应 3.0h， 生成 p-Methoxy-propiophenon-hydrazon
  参考文献：
  名称：

  肼介导的镍催化酮的立体选择性烯基化

  摘要：

  天然丰富的羰基化合物的直接转化为高效合成有价值的化学品提供了强大的平台。特别是，酮转化为烯烃是一种常见的化学转化，通常通过与甲苯磺酰腙和超过化学计量的有机锂或格氏试剂的多步夏皮罗反应来实现。在此，我们报道了一种地球丰富的镍催化天然丰富的亚甲基酮的烯基化反应，以提供由肼介导的多种烯烃衍生物。该方案具有广泛的底物范围（包括烷基酮、芳基酮和醛）、良好的官能团相容性、温和的反应条件、耐水性，并且仅对环境友好的N 2、H 2和H 2O 作为理论副产品。此外，具有良好收率和产生药物中间体的克级合成突出了其实际适用性。

  DOI：

  10.1021/jacsau.2c00320

文献信息

• v. Vargha; Kovacs, Chemische Berichte, 1942, vol. 75, p. 794,802
  作者：v. Vargha、Kovacs

  DOI：——

  日期：——
• Personal Collections: Women's clothing use and identity
  作者：Alison Guy、Maura Banim

  DOI：10.1080/713678000

  日期：2000.11

  Women's relationship with clothes has been explored within a range of theoretical discourses about fashion that utilise the concept of ambivalence. This paper acknowledges that this may be a useful conceptualisation but argues that there is an absence of focus in most of these approaches concerning the reality of women using, reflecting on and generally living with their clothes. Using original research with a sample of 15 women, this paper attempts to integrate existing approaches and explore the complexity and ongoing-ness of the process of self-presentation through clothes. It argues that women have an dynamic relationship with their clothes that can be grouped around three co-existing views of self; 'The woman I want to be', 'The woman I fear I could be' and 'The woman I am most of the time'. These three views illustrate women's attempts to achieve satisfying images as they engage with clothes to create, reveal or conceal aspects of their identity. A range of social constraints is evident but the accounts also reveal that the women often endeavour to challenge, subvert and rise above these constraints. Furthermore, these endeavours are likely to be experienced as pleasurable, making clothes selection and use a positive force in women's lives.
• Process of making dialkyl stilboestrols
  申请人：LASZLO VARGHA

  公开号：US02305748A1

  公开（公告）日：1942-12-22