2,6-(t-BuOCH2)2C6H3Sb(trifluoroacetato)2 | 950767-94-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 2,6-(t-BuOCH2)2C6H3Sb(trifluoroacetato)2
• CAS: 950767-94-9
• 化学式: C₂₀H₂₅F₆O₆Sb
• 分子量: 597.155
• InChiKey: SGYJMLTWJGSMJE-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2,6-(t-BuOCH2)2C6H3SbCl2 、 silver trifluoroacetate 以 二氯甲烷 为溶剂， 以65%的产率得到2,6-(t-BuOCH2)2C6H3Sb(trifluoroacetato)2
  参考文献：
  名称：

  Intramolecularly coordinated organoantimony(III) carboxylates

  摘要：

  The reactions of organoantimony chlorides (LSbCl2)-Sb-1,2 1 and 2 ([2,6-(ROCH2)(2)C6H3](-), R = Me; L-1 and R = t-Bu; L-2) with silver salts of selected carboxylic acids resulted to corresponding organoantimony carboxylates L-1,L-2 Sb(OOCR')(2), 1a-c (for L-1) and 2a-c (for L-2), where R'= CH3 for la, 2a; R' = CH=CH2 for 1b, 2b and R'= CF3 for 1c, 2c. All compounds were characterized by the help of elemental analysis, ESI-MS, H-1 and C-13 NMR spectroscopy. The solid state structure investigation using single crystal X-ray diffraction techniques (2a, c) and IR spectroscopy revealed significant differences in coordination mode of both O,C,O chelating ligand and carboxylic groups in this set of compounds. The structure of all compounds in solution of non-coordinating solvent (CDCl3) was determined by means of variable temperature H-1, C-13, F-19 NMR spectroscopy and IR spectroscopy. (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2007.06.005