1,4,8,11,15,18,22,25-octakis(pentylthiophthalocyaninato)palladium(II) | 1190872-36-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 四吡咯及其衍生物
• 英文名称: 1,4,8,11,15,18,22,25-octakis(pentylthiophthalocyaninato)palladium(II)
• 英文别名: palladium 1,4,8,11,15,18,22,25-octakis(pentylthio)phthalocyanine；1,4,8,11,15,18,22,25-octakis(pentylthiophthalocyaninato) palladium
• CAS: 1190872-36-6
• 化学式: C₇₂H₉₆N₈PdS₈
• 分子量: 1436.56
• InChiKey: YUSMSZAAEWTKQV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  3,6-dipentylthiophthalonitrile 、 palladium dichloride 在 1,8-二氮杂双环[5.4.0]十一碳-7-烯 作用下， 以 戊醇 为溶剂， 以40%的产率得到1,4,8,11,15,18,22,25-octakis(pentylthiophthalocyaninato)palladium(II)
  参考文献：
  名称：

  Synthesis and Pd(II) binding studies of octasubstituted alkyl thio derivatised phthalocyanines

  摘要：

  Synthesis and characterization of non-peripherally (4,5) and peripherally (6,7) substituted metal free and Pd octapentylthiophthalocyanine and coordination of palladium ions to these Pcs are reported. The unmetalated complexes (4 and 6) show Id coordination at the central metal and at the ring. The number of Id ions bound to complex 4 were found to be five and to complex 6 were three. The equilibrium constant for the binding of Pd to complexes 4 was lower (K = 1.2 x 10(9) dm(3) Mol(-1)) than for complex 6 (K = 5.7 x 10(10) dm(3) mol(-1)). (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2009.05.026