Ni(1-cyclohexyl-3-tosylurea(-H))2(water)2 | 1093747-03-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Ni(1-cyclohexyl-3-tosylurea(-H))2(water)2
• CAS: 1093747-03-5
• 化学式: C₂₈H₄₂N₄NiO₈S₂
• 分子量: 685.485
• InChiKey: WYQLTHXSRCVXDU-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  nickel(II) nitrate hexahydrate 、 格列环脲 在 CH₃CH₂ONa 作用下， 以 乙醇 为溶剂， 生成 Ni(1-cyclohexyl-3-tosylurea(-H))2(water)2
  参考文献：
  名称：

  Synthesis, characterization and DNA-binding studies of 1-cyclohexyl-3-tosylurea and its Ni(II), and Cd(II) complexes

  摘要：

  1-Cyclohexyl-3-tosylurea (HL) and its two complexes, ML2 center dot 2H(2)O [M=Ni (1), and Cd(2)], have been synthesized and characterized on the basis of elemental analyses, molar conductivities, IR spectra and thermal analyses. In addition, the DNA-binding properties of the ligand and the two complexes have been investigated by electronic absorption, fluorescence, CD spectroscopy and viscosity measurements. The experiment results suggest that the ligand and its two complexes bind to DNA via a groove binding mode, and the binding affinity of the complex 2 is higher than that of the complex I and the ligand. (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.saa.2008.01.005