(N,N-dipropyldithiocarbamato-S,S')tetraphenylantimony(V) | 880132-21-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (N,N-dipropyldithiocarbamato-S,S')tetraphenylantimony(V)
• CAS: 880132-21-8
• 化学式: C₃₁H₃₄NS₂Sb
• 分子量: 606.5
• InChiKey: BZUCSXHRTJXAHO-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  bis(N,N-dipropyldithiocarbamato-S,S')tri(p-tolyl)antimony(V) 、 pentaphenylantimony 以 正己烷 为溶剂， 以83%的产率得到(N,N-dipropyldithiocarbamato-S,S')tetraphenylantimony(V)
  参考文献：
  名称：

  Tetraphenyl-and tetratolylantimony complexes with N,N-dialkyldithiocarbamate ligands: Synthesis, X-ray diffraction analysis, and 13C and 15N CP/MAS NMR studies

  摘要：

  Crystalline tetraphenylantimony and tetratolylantimony complexes with N,N-dialkyldithiocarbamate ligands [Sb(C6H5)(4)(S2CNR2)] (R = CH3, C2H5, and C3H7 and R-2 = (CH2)(6)) were synthesized by ligand exchange reactions and studied by C-13 and N-15 CP/MAS NMR spectroscopy. X-ray diffraction analysis revealed that the complex [Sb(n-CH3-C6H4)(4){S2CN(C3H7)(2))] exists as the single molecular form, while [Sb(C6H5)(4){ S2CN(CH2)(6))] exists as two molecular conformers. The 13C and 15N signals were assigned to the C, positions of the atoms in the isomeric structures [Sb(C6H5)(4)[S2CN(CH2)(6)}] in terms of different degrees of double bonding in the formally single =N-C(S)S- bond.

  DOI：

  10.1134/s1070328406060017