Cu(bis-N,N'-(salicylidene)-1,3-propanediamine(-2H))(H2O) | 252325-10-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Cu(bis-N,N'-(salicylidene)-1,3-propanediamine(-2H))(H2O)
• CAS: 252325-10-3
• 化学式: C₁₇H₁₈CuN₂O₃
• 分子量: 361.888
• InChiKey: GTZGUIVEGBOLQU-RDGKIGCSSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  Cu(bis-N,N'-(salicylidene)-1,3-propanediamine(-2H))(H2O) 以 neat (no solvent) 为溶剂， 生成 copper(II) oxide
  参考文献：
  名称：

  Estimation of coordination bond energies of NH3, H2O and Et2NH ligands in the Ni(II) and Cu(II) complexes

  摘要：

  以三齿配体2-羟基苯基水杨醛亚胺（SAPH2）、2-羟基苯基-2-羟基-1-萘醛亚胺（NAPH2）以及多齿配体双-N·N′-（水杨醛）-1,3-丙二胺（LH2）与Ni（II）的配合物和单核Cu（II）配合物为研究对象，采用相同的L2配体合成这些配合物，并将单齿配体二乙胺（Et2NH）、NH3和H2O以配位键形式与其键合。利用TG和DSC方法测定配体热分解脱除时的温度，并测得这些配合物在配体热分解时的热效应。假定有单齿配体和没有单齿配体的配合物均为固态，计算了单齿配体的配位键能，发现这些计算得到的配位键能与氢键键能相当。

  DOI：

  10.1007/s10973-009-0176-3
• 作为产物：
  描述：

  水 、 {copper(II)-(N,N'-disalicylidene-1,3-propanediamine)} 以 乙醇 、 水 为溶剂， 生成 Cu(bis-N,N'-(salicylidene)-1,3-propanediamine(-2H))(H2O)
  参考文献：
  名称：

  Estimation of coordination bond energies of NH3, H2O and Et2NH ligands in the Ni(II) and Cu(II) complexes

  摘要：

  以三齿配体2-羟基苯基水杨醛亚胺（SAPH2）、2-羟基苯基-2-羟基-1-萘醛亚胺（NAPH2）以及多齿配体双-N·N′-（水杨醛）-1,3-丙二胺（LH2）与Ni（II）的配合物和单核Cu（II）配合物为研究对象，采用相同的L2配体合成这些配合物，并将单齿配体二乙胺（Et2NH）、NH3和H2O以配位键形式与其键合。利用TG和DSC方法测定配体热分解脱除时的温度，并测得这些配合物在配体热分解时的热效应。假定有单齿配体和没有单齿配体的配合物均为固态，计算了单齿配体的配位键能，发现这些计算得到的配位键能与氢键键能相当。

  DOI：

  10.1007/s10973-009-0176-3

文献信息

• First examples of 3d-uranium compounds derived from single-compartment Schiff base ligands: Syntheses, crystal structures and d–d band correlation
  作者：Leena Mandal、Sagarika Bhattacharya、Sasankasekhar Mohanta

  DOI：10.1016/j.ica.2013.07.012

  日期：2013.9

  This paper deals with the syntheses, characterization, crystal structures and UV-Vis spectroscopy of three diphenoxo-bridged dinuclear Cu-II((UO2)-O-VI) compounds [Cu-II(MeCN)L-1((UO2)-O-VI)(NO3)(2)] (1), [Cu-II(MeCN)L-2((UO2)-O-VI)(NO3)(2)] (2) and [Cu-II(MeCN)L-3((UO2)-O-VI)(NO3)(2)] (3) derived from the single-compartment Schiff base ligands H2L1 (2:1 condensation product of salicylaldehyde and 1,3-diaminopropane), H2L2 (2:1 condensation product of salicylaldehyde and 1-ethyl-1,3-diaminopropane) and H2L3 (2:1 condensation product of 2-hydroxyacetophenone and 1,3-diaminopropane). While copper(II) occupies the N2O2 compartment, uranium(VI) center is linked with Schiff base ligand through the two bridging phenoxo oxygen atoms. Copper(II) is pentacoordinated and distorted square pyramidal, while the uranium(VI) center is octaco-ordinated and distorted hexagonal bipyramidal in which the two uranyl oxygen atoms occupy the apical positions. Electronic spectra of 1-3 and the corresponding mononuclear Cu-II compounds have been recorded and a previously reported but practically unexplored correlation regarding d-d band position has been highlighted. Although the correlation is not valid for only mononuclear or only dinuclear compounds derived from different ligands, a nice correlation is found out on comparing the spectra of dinuclear compounds with the corresponding mononuclear compounds. (C) 2013 Elsevier B.V. All rights reserved.
• Exploration of heterometallic systems containing silver(I) in acyclic Schiff base ligands: Finite and infinite self-assemblies as a result of silver(I)–carbon bond and silver(I)⋯silver(I) interaction
  作者：Arpita Biswas、Suraj Mondal、Leena Mandal、Arpita Jana、Priyanka Chakraborty、Sasankasekhar Mohanta

  DOI：10.1016/j.ica.2014.01.045

  日期：2014.4

  The work in this report describes the syntheses and crystal structures of nine copper(II)-silver(I) compounds derived from some single-compartment N(imine)(2)O(phenoxo)(2) or double-compartment N(imine)(2)O(phenoxo)(2)-O(phenoxo)(2)O(methoxy/ethoxy)(2) acyclic Schiff base ligands. The nine compounds are [Cu-II(ClO4)(Lsal-enAgI)}(2)Cu-II(ClO4)(Lsal-enAgI)(H2O)}](n) (1), [(CuLsal-pnAgI)-L-II(ClO4)](n) (2), [(CuLsal-pnAgI)-L-II(NO3)}(2)] (3), [((CuLacpn-en)-L-II)(2)Ag-I(MeCN)(2)](ClO4) (4), [(CuLOMe-enAgI)-L-II(NO3)}(2)] (5), [(CuLOMe-pnAgI)-L-II(NO3)}(2)] (6), [(CuLOMe-pnAgI)-L-II(NO3)}(2)]center dot 2H(2)O (7), [(CuLOEt-enAgI)-L-II(NO3)}(2)] (8) and [(CuLOEt-opAgI)-L-II(MeOH)}(2)](ClO4)(2) (9), where the superscripts in the ligand symbols mean the following: (i) sal, acpn, OMe and OEt indicate that the aldehyde counterpart is salicylaldehyde, 2-hydroxyacetophenone, 3-methoxysalicylaldehyde and 3-ethoxysalicylaldehyde, respectively; (ii) en, pn and op indicate that the diamine counterpart is ethylenediamine, 1,3-diaminopropane and o-phenylenediamine, respectively. Copper(II) in all these compounds occupies a N2O2 compartment and the two phenoxo oxygen atoms in all cases bridge one copper(II) and one silver(I) centers. Compound 4 is a trinuclear (CuAgCuII)-Ag-II-Cu-I system. Compounds 3 and 5-9 are dimer-of-dinuclear compounds, in which the dimerization takes place due to interdinuclear Cu-O(nitrate) and Ag center dot center dot center dot Ag interactions in 3, 5 and 6 and due to Ag-pi (eta(1)-/eta(2)-) bonds in 7-9. Compounds 2 and 1 are one-dimensional coordination polymers due to Ag-pi (eta(2)-)/Ag-pi (eta(3)-) bonds. CSD search/ analysis reveals some definite significant aspects in both the Ag-pi and Ag-pi (eta(3)-) bonds. CSD search/analysis reveals some definite significant aspects in both the Ag-pi and Ag center dot center dot center dot Ag bonded systems in the present investigation. (C) 2014 Elsevier B. V. All rights reserved.
• Aqua[<i>N</i>,<i>N</i>'-bis(salicylidene)-1,3-propanediaminato]copper(II)
  作者：C. Arıcı、F. Ercan、O. Atakol、O. Cakırer

  DOI：10.1107/s010827019900894x

  日期：1999.10.15

  The title compound, [Cu(C17H16N2O2)(H2O)], has m symmetry. The Cu atom has an approximately square-pyramidal environment involving the two O atoms and two N atoms of the N,N'-bis(salicylidene)-1,3-propanediaminate ligand and one O atom of the water molecule in the apical position. In the coordination sphere, the O-Cu-N and N-Cu-O(water) angles are 89.6(1) and 96.7 (1)degrees, respectively.