N,N-diphenylacridin-9-amine | 107317-20-4

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N,N-diphenylacridin-9-amine
• 英文别名: 9-(diphenylamine)acridine；9-diphenylaminoacridine；9-DPAA
• CAS: 107317-20-4
• 化学式: C₂₅H₁₈N₂
• 分子量: 346.431
• InChiKey: SVJJFTCOHJRTOB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.8
• 重原子数：
  27
• 可旋转键数：
  3
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  16.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  N,N-diphenylacridin-9-amine 在 盐酸 作用下， 以 甲醇 为溶剂， 生成 N,N-diphenylacridin-9-amine hydrochloride
  参考文献：
  名称：

  9-diphenylaminoacridines as molecular fluorescent chemosensors for determining polar solvent and amine vapors

  摘要：

  The results of study of the photophysical properties of three fluorophores from the 9-diphenylaminoacridine series in solutions are presented. It has been shown that the photoinduced synthesis of 9-diphenylaminoacridines in polymer films and on the surface of polymeric micro- and nanoparticles can be used for detection of polar solvent and amine vapors.

  DOI：

  10.1134/s0018143913060076
• 作为产物：
  描述：

  二苯胺 、 9-氯吖啶 在 tris-(dibenzylideneacetone)dipalladium(0) 、 三叔丁基膦 、 potassium tert-butylate 作用下， 以 苯 为溶剂， 以75.1 %的产率得到N,N-diphenylacridin-9-amine
  参考文献：
  名称：

  荧光寿命成像揭示细胞内脂肪分解和巨噬细胞泡沫中意想不到的 omega-3 活性

  摘要：

  美国国家科学院院刊，第 121 卷，第 15 期，2024 年 4 月。

  DOI：

  10.1073/pnas.2321255121

文献信息

• FLUORANTHENE DERIVATIVE, LUMINESCENT ELEMENT MATERIAL CONTAINING SAME, AND LUMINESCENT ELEMENT
  申请人：Toray Industries, Inc.

  公开号：EP2907803A1

  公开（公告）日：2015-08-19

  The purpose of the present invention is to provide an organic thin-film luminescent element which exhibits improved luminous efficiency, drive voltage and durability life. This fluoranthene derivative is characterized by having a specificstructure that contains a fluoranthene skeleton.

  本发明的目的是提供一种有机薄膜发光元件，其发光效率、驱动电压和耐用寿命均有所提高。这种荧蒽衍生物的特点是具有包含荧蒽骨架的特定结构。
• Compositions and methods of promoting organic photocatalysis
  申请人：THE REGENTS OF THE UNIVERSITY OF COLORADO, A BODY CORPORATE

  公开号：US10975171B2

  公开（公告）日：2021-04-13

  The invention provides novel compounds and methods that are useful in promoting reactions that proceed through an oxidative quenching pathway. In certain embodiments, the reactions comprise atom transfer radical polymerization.

  本发明提供了有助于促进通过氧化淬灭途径进行的反应的新型化合物和方法。在某些实施方案中，反应包括原子转移自由基聚合。
• Photoinduced bimolecular cyclization of diarylamines and polyhalogenomethanes into acridines
  作者：M. F. Budyka

  DOI：10.1007/bf00702130

  日期：1995.2

  The spectral and kinetic properties of the intermediates in the photoinduced reaction of diarylaminoacridine formation from diarylamine and tetrabromomethane are studied. The data obtained are explained in terms of the following scheme: the recombination of primary radicals to the methyleneiminium salt followed by the alkylation of the second amine molecule at the ortho-position and the cyclization into the final product.
• Synthesis, structure and spectral properties of 9-diarylamino-substituted acridines
  作者：Viacheslav A. Sazhnikov、Artem A. Khlebunov、Sergey K. Sazonov、Artem I. Vedernikov、Andrei A. Safonov、Alexander A. Bagatur’yants、Lyudmila G. Kuz’mina、Judith A.K. Howard、Sergey P. Gromov、Michael V. Alfimov

  DOI：10.1016/j.molstruc.2013.09.001

  日期：2013.12

  The synthesis of three 9-diarylamino-substituted acridines is reported. The compounds of the donor-acceptor type - N,N-diphenylacridin-9-amine (1), 2,7-dimethyl-N,N-bis(4-methylphenyl)acridin-9-amine (2), and 2,7-bis(1-methyl-1-phenylethyl)-N,N-bis[4-(1-methyl-1-phenylethyl)phenyl]acridin-9-amine (3) were characterized by IR, H-1 and C-13 NMR. mass-spectral and elemental analysis. The crystal structures of compounds 1-3 and their protonated forms were determined by X-ray diffraction analysis. The absorption and fluorescence spectra were measured in various solvents. Solvatochromic shifts and dependence of the fluorescence quantum yields on the solvent polarity and protonation suggest the use of these compounds as chemical sensors. An example of a sensor material based on compound 2 is presented. Density functional theory calculations of the structures and time-dependent density functional theory calculations of the gas-phase excitation and emission energies of 1 were performed at the PBE0/SVP level of theory. (C) 2013 Elsevier B.V. All rights reserved.
• Hydrogen atom transfer and triplet exciplexes in photochemical reactions of acridine and 9-chloroacridine with aromatic amines
  作者：P. P. Levin、V. A. Kuz'min、R. M. Fatkulbayanov、M. F. Budyka、M. V. Alfimov

  DOI：10.1007/bf00953601

  日期：1989.2