1,2,5-triiodo-3-methylbenzene | 89677-86-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,2,5-triiodo-3-methylbenzene
• 英文别名: 2,3,5-triiodo-toluene；2,3,5-Trijod-toluol；2,3,5-Triiod-toluol；2,3,5-Triiodotoluol；2.3.5-Trijod-toluol
• CAS: 89677-86-1
• 化学式: C₇H₅I₃
• 分子量: 469.83
• InChiKey: YMZNUPTUGITAHW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  10
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  2,3-二碘-5-硝基-甲苯 在 ammonium hydroxide 、 iron(II) sulfate 作用下， 生成 1,2,5-triiodo-3-methylbenzene
  参考文献：
  名称：

  碘化和碘化合物。第三部分 在20％的发烟硫酸中用碘对某些芳香族硝基化合物进行碘化

  摘要：

  描述了在20％发烟硫酸中使用碘来碘化一系列芳族硝基化合物。包括实现反应所需的条件和产品身份证明。该系统已经被发现表现为亲电试剂，但它不会引进和碘原子邻位的硝基的基团。

  DOI：

  10.1039/j39700001480

文献信息

• A Mild and Convenient Synthesis of 1,2,3-Triiodoarenes via Consecutive Iodination/Diazotization/Iodination Strategy
  作者：Raed M. Al-Zoubi、Hassan Abul Futouh、Robert McDonald

  DOI：10.1071/ch13324

  日期：——

  A mild and convenient synthesis of 1,2,3-triiodoarenes has been developed. This method consists of two steps which can be performed on multigram scale with moderate to excellent yields. This report discloses a practical synthesis of 1,2,3-triiodoarenes and 1,2,3-trihaloarenes that is general in scope, operationally simple, scalable, and is easy to workup and to purify. We also report the first regioselective transmetalation reaction of 1,2,3-triiodoarenes to provide ortho-diiodoaryl derivatives, which are useful building blocks and indeed are hard to make by other means.

  我们开发了一种温和、简便的 1,2,3-三碘烯烃合成方法。该方法由两个步骤组成，可在多克级规模上进行，产率为中等至极佳。本报告揭示了 1,2,3-三碘烯烃和 1,2,3-三卤代烯烃的实用合成方法，该方法范围广泛、操作简单、可扩展、易于加工和纯化。我们还首次报告了 1,2,3-三碘烯烃的区域选择性反金属化反应，以提供正二碘芳基衍生物，这些衍生物是有用的构筑基块，实际上很难通过其他方法制造。
• Electrolyte additive and electrolyte including same and lithium rechargeble battery including electrolyte
  申请人：Samsung SDI Co., Ltd.

  公开号：EP2746288A1

  公开（公告）日：2014-06-25

  Disclosed is an electrolyte additive represented by the following Chemical Formula 1, and an electrolyte for a rechargeable lithium battery including the electrolyte additive, and a rechargeable lithium battery including the electrolyte. In Chemical Formula 1, R1 to R4 are the same as defined in the detailed description.

  公开了一种由以下化学式1表示的电解质添加剂，以及包括该电解质添加剂的可充电锂电池的电解质，以及包括该电解质的可充电锂电池。在化学式1中，R1至R4的定义与详细说明中的相同。
• Electrolyte for rechargeable lithium battery and rechargeable lithium battery
  申请人：SAMSUNG SDI CO., LTD.

  公开号：US10998580B2

  公开（公告）日：2021-05-04

  An electrolyte for a rechargeable lithium battery and a rechargeable lithium battery including the electrolyte, the electrolyte including a non-aqueous organic solvent; a lithium salt; and an additive, wherein the additive includes a compound represented by Chemical Formula 1: wherein, in Chemical Formula 1, R is a substituted or unsubstituted C1 to C10 alkyl group, a substituted or unsubstituted C1 to C10 alkoxy group, a substituted or unsubstituted C2 to C10 alkenyl group, a substituted or unsubstituted C2 to C10 alkynyl group, a substituted or unsubstituted C3 to C10 cycloalkyl group, a substituted or unsubstituted C3 to C10 cycloalkenyl group, or a substituted or unsubstituted C6 to C20 aryl group, and n is an integer of 1 to 3.

  一种用于可充电锂电池的电解质和包括该电解质的可充电锂电池，所述电解质包括非水有机溶剂；锂盐；和添加剂，其中所述添加剂包括化学式1所表示的化合物： 在化学式1中，R是取代或未取代的C1至C10烷基，取代或未取代的C1至C10烷氧基，取代或未取代的C2至C10烯基，取代或未取代的C2至C10炔基，取代或未取代的C3至C10环烷基，取代或未取代的C3至C10环烯基或取代或未取代的C6至C20芳基，n为1至3的整数。
• ELECTROLYTE FOR RECHARGEABLE LITHIUM BATTERY AND RECHARGEABLE LITHIUM BATTERY
  申请人：SAMSUNG SDI CO., LTD.

  公开号：US20210135287A1

  公开（公告）日：2021-05-06

  An electrolyte for a rechargeable lithium battery and a rechargeable lithium battery including the electrolyte, the electrolyte including a non-aqueous organic solvent; a lithium salt; and an additive, wherein the additive includes a compound represented by Chemical Formula 1: in Chemical Formula 1, R 1 is a cyano group, a substituted or unsubstituted C2 to C10 alkenyl group, or a substituted or unsubstituted C2 to C10 alkynyl group.

  一种可充电锂电池的电解质以及包括该电解质的可充电锂电池，该电解质包括非水有机溶剂、锂盐和添加剂，其中该添加剂包括化学式1所表示的化合物：在化学式1中，R1是氰基、取代或未取代的C2到C10烯基基团或取代或未取代的C2到C10炔基基团。
• Electrolyte additive and electrolyte including the same and rechargeable lithium battery including the electrolyte
  申请人：Samsung SDI Co., Ltd.

  公开号：EP2660920A2

  公开（公告）日：2013-11-06

  An electrolyte additive represented by chemical formula 1, for use in a rechargeable lithium battery, and an electrolyte solution including same; wherein X1 to X5 are each independently a halogen atom or a halogen-containing group; and Z is represented by *-NR1R2.

  一种化学式 1 所代表的电解质添加剂，用于可充电锂电池，以及包括该添加剂的电解质溶液； 其中 X1 至 X5 各自独立地为卤原子或含卤基团；Z 由 *-NR1R2 表示。