meso-1,2-dibromo-1,2-dideuterio-ethane | 86860-52-8

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机溴化物
• 英文名称: meso-1,2-dibromo-1,2-dideuterio-ethane
• 英文别名: meso-1,2-Dibrom-1,2-dideuterio-aethan；Ethane-1,2-d2, 1,2-dibromo-, (R*,S*)-；(1R,2S)-1,2-dibromo-1,2-dideuterioethane
• CAS: 86860-52-8
• 化学式: C₂H₄Br₂
• 分子量: 189.846
• InChiKey: PAAZPARNPHGIKF-CTMXUUQZSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2
• 重原子数：
  4
• 可旋转键数：
  1
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  meso-1,2-dibromo-1,2-dideuterio-ethane 在 甲醇 、 potassium iodide 作用下， 生成 1,2-dideuterioethene
  参考文献：
  名称：

  The Stereochemistry of the Debromination of meso-1,2-Dibromo-1,2-dideuteroethane by Iodide Ion

  摘要：

  DOI：

  10.1021/ja01626a098
• 作为产物：
  描述：

  1,2-diprotioethene 在 水 、 溴 、 potassium bromide 作用下， 生成 meso-1,2-dibromo-1,2-dideuterio-ethane
  参考文献：
  名称：

  Rotational Isomerism and the Vibrational Spectrum ofSym‐Dideuterodibromoethane

  摘要：

  Trans-ethylene-d2 was brominated by two methods, which involved different stereochemical paths, to give 95 percent meso-BrDHC-CHDBr as one product and a mixture of meso- and racemic-BrDHC-CHDBr as the other. Liquid phase Raman spectra and liquid and solid phase infrared spectra of these materials have been obtained and a tentative assignment of the vibrational frequencies of BrDHC-CHDBr to the trans and skew configurations of the meso and racemic compounds has been made.

  DOI：

  10.1063/1.1700716

文献信息

• The Stereochemistry of the Debromination of Vicinal Dibromides by Metals¹
  作者：W. M. Schubert、B. S. Rabinovitch、N. R. Larson、V. A. Sims

  DOI：10.1021/ja01138a042

  日期：1952.9
• PETERSON, LISA A.;HARRIS, THOMAS M.;GUENGERICH, F. PETER, J. AMER. CHEM. SOC., 110,(1988) N 10, 3284-3291
  作者：PETERSON, LISA A.、HARRIS, THOMAS M.、GUENGERICH, F. PETER

  DOI：——

  日期：——
• The Stereochemistry of the Debromination of meso-1,2-Dibromo-1,2-dideuteroethane by Iodide Ion
  作者：W. M. Schubert、Harvey Steadly、B. S. Rabinovitch

  DOI：10.1021/ja01626a098

  日期：1955.11
• Rotational Isomerism and the Vibrational Spectrum of<i>Sym</i>‐Dideuterodibromoethane
  作者：H. J. Bernstein、A. D. E. Pullin、B. S. Rabinovitch、N. R. Larson

  DOI：10.1063/1.1700716

  日期：1952.8

  Trans-ethylene-d2 was brominated by two methods, which involved different stereochemical paths, to give 95 percent meso-BrDHC-CHDBr as one product and a mixture of meso- and racemic-BrDHC-CHDBr as the other. Liquid phase Raman spectra and liquid and solid phase infrared spectra of these materials have been obtained and a tentative assignment of the vibrational frequencies of BrDHC-CHDBr to the trans and skew configurations of the meso and racemic compounds has been made.