(1,2-bis(diphenylphosphino)ethane)(CH3)Pd(NO3) | 64367-40-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (1,2-bis(diphenylphosphino)ethane)(CH3)Pd(NO3)
• 英文别名: PdMe(NO3)(1,2-bis(diphenylphosphino)ethane)；(dppe)PdMe(NO3)
• CAS: 64367-40-4
• 化学式: C₂₇H₂₇NO₃P₂Pd
• 分子量: 581.884
• InChiKey: SJVWVIOOQPJRDM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  (1,2-bis(diphenylphosphino)ethane)(CH3)Pd(NO3) 以 四氢呋喃 为溶剂， 生成 [Pd(COMe)(aziridine)(1,2-bis(diphenylphosphino)ethane)](Co(CO)4)
  参考文献：
  名称：

  Synthesis and reactions of heterodinuclear organopalladium–cobalt complexes acting as copolymerization catalyst for aziridine and carbon monoxide

  摘要：

  A series of heterodinuclear acylpalladium-cobalt complexes having a bidentate nitrogen ligand, L-2(RCO)Pd-Co(CO)(4) (L-2 = bpy, R = Me (5), Ph (6); L-2 = tmeda, R = Me (7), Ph (8); L-2 = phen, R = Me (9), Ph (10)) are prepared by metathetical reactions of PdRIL2 with Na+[Co(CO)(4)](-) followed by treatment with CO. These complexes are characterized by NMR and IR spectroscopies and elemental analyses, and the molecular structures of 6, 8, and 9 are determined by X-ray structure analysis. Geometry at Pd is essentially square planar and the Cc atom is considered to have d(10) tetrahedral structure, where cobalt(-I) anion coordinates to palladium(II) cation. Heterodinuclear organopalladium-cobalt complexes are shown to catalyze copolymerization of aziridines and CO under mild conditions. Reaction of (dppe)MePd-Co(CO)(4) (1) with aziridine gives a cationic (aziridine)palladium(II) complex with [CO(CO)(4)](-) anion, [PdMe(aziridine)(dppe)](+)[CO(CO)(4)](-) (13). (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2006.04.044

文献信息

• Oxidative Addition of Organocobalt(I) and -molybdenum(II) Complexes to Palladium(0) Complexes To Give Heterodinuclear Organometallic Complexes
  作者：Nobuyuki Komine、Hideko Hoh、Masafumi Hirano、Sanshiro Komiya

  DOI：10.1021/om000728o

  日期：2000.12.1

  Oxidative addition of Co(COMe)(CO)4 and MoMeCp(CO)3 to Pd(dba)2 (dba = dibenzylideneacetone) in the presence of the bidentate ligand L2 (L2 = dppe (1,2-bis(diphenylphosphino)ethane), tmeda (N,N,N‘,N‘-tetramethylethylenediamine), bpy (2,2‘-bipyridine), phen (1,10-phenanthroline)) takes place to give L2(MeCO)Pd−Co(CO)4 (L2 = dppe (1), tmeda (2), bpy (3), phen (4)) and (dppe)MePd−MoCp(CO)3 (5), respectively

  在双齿配体L 2（L 2 = dppe（1,2-双（二苯基二膦））存在下，将Co（COMe）（CO）4和MoMeCp（CO）3氧化成Pd（dba）2（dba =二苄叉基丙酮））乙烷），tmeda（N，N，N '，N'-四甲基乙二胺），bpy（2,2'-联吡啶），phen（1,10-菲咯啉））生成L 2（MeCO）Pd-Co （CO）4（L 2 = dppe（1），tmeda（2），bpy（3），phen（4））和（dppe）MePd-MoCp（CO）3（5）， 分别。