Tris(3-chlorophenyl)-sulfanylidene-lambda5-phosphane | 54300-45-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Tris(3-chlorophenyl)-sulfanylidene-lambda5-phosphane
• 英文别名: tris(3-chlorophenyl)-sulfanylidene-λ5-phosphane
• CAS: 54300-45-7
• 化学式: C₁₈H₁₂Cl₃PS
• 分子量: 397.692
• InChiKey: BGPJXNQOCQVIHL-UHFFFAOYSA-N

物化性质

• 沸点：
  517.4±60.0 °C(Predicted)
• 密度：
  1.43±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7.7
• 重原子数：
  23
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  32.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  diphenyl trisulfide 、 三(3-氯苯基)膦 以 氘代甲苯 、 甲苯 为溶剂， 生成 Tris(3-chlorophenyl)-sulfanylidene-lambda5-phosphane 、 二苯二硫醚
  参考文献：
  名称：

  Hall, C. Dennis; Tweedy, Bruce R.; Kayhanian, Robert, Journal of the Chemical Society. Perkin transactions II, 1992, # 2, p. 775 - 779

  摘要：

  DOI：

文献信息

• Magic Size Nanoclusters and Methods of Preparing Same
  申请人：Krauss Todd D.

  公开号：US20110052918A1

  公开（公告）日：2011-03-03

  Disclosed herein are magic size nanoclusters comprising lead and one or more chalcogens. The disclosed magic size nanoclusters have both spectrally narrow fluorescence and ultra-high quantum efficiencies. Further disclosed herein is a method for preparing PbS, PbSe, and PbTe magic size nanoclusters. The yield of magic size nanoclusters can be increased by using anion sources enriched for secondary phosphines. The use of enriched secondary phosphine anion sources also increases the yield of quantum nanostructures.
• US8617707B2
  申请人：——

  公开号：US8617707B2

  公开（公告）日：2013-12-31
• [EN] MAGIC SIZE NANOCLUSTERS AND METHODS OF PREPARING SAME<br/>[FR] NANOAGRÉGATS DE TAILLE MAGIQUE ET LEURS PROCÉDÉS DE PRÉPARATION
  申请人：UNIV ROCHESTER

  公开号：WO2009120688A1

  公开（公告）日：2009-10-01

  Disclosed herein are magic size nanoclusters comprising lead and one or more chalcogens. The disclosed magic size nanoclusters have both spectrally narrow fluorescence and ultra-high quantum efficiencies. Further disclosed herein is a method for preparing PbS, PbSe, and PbTe magic size nanoclusters. The yield of magic size nanoclusters can be increased by using anion sources enriched for secondary phosphines. The use of enriched secondary phosphine anion sources also increases the yield of quantum nanostructures.