| 240814-62-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 240814-62-4
• 化学式: C₁₃H₁₁CeN₃O₈S
• 分子量: 509.432
• InChiKey: WWSPBFAKUNLMJN-GPZOHOMCSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  以 neat (no solvent) 为溶剂， 生成
  参考文献：
  名称：

  Preparation, Characterization and Thermal Study of New Cerium(IV) Complexes with the Salicylidene-2-Aminothiophenol Schiff Base

  摘要：

  New complexes of the titled Schiff base with cerium(IV) ion have been synthesized and characterized by elemental analyses, conductimetric, IR and H-1 NMR studies and thermogravimetric analysis. The results suggest that the Schiff base acts as a bivalent anion with tridentate ONS donors derived from the phenolic oxygen, azomethine nitrogen and thiophenolic sulfur. The complexes formed are non-electrolytes with the general formulae [ML(NO3)(2)H2O] and [M(HL)(2)(NO3)(2)]. The thermal decomposition of the complexes follows first order kinetics and the thermodynamic parameters of the decomposition are reported.

  DOI：

  10.1080/00945719909349517
• 作为产物：
  描述：

  ceric ammonium nitrate 、 2-(亚水杨基氨基)硫代苯酚 在 ammonium hydroxide 作用下， 以 乙醇 、 水 为溶剂， 以90%的产率得到
  参考文献：
  名称：

  Preparation, Characterization and Thermal Study of New Cerium(IV) Complexes with the Salicylidene-2-Aminothiophenol Schiff Base

  摘要：

  New complexes of the titled Schiff base with cerium(IV) ion have been synthesized and characterized by elemental analyses, conductimetric, IR and H-1 NMR studies and thermogravimetric analysis. The results suggest that the Schiff base acts as a bivalent anion with tridentate ONS donors derived from the phenolic oxygen, azomethine nitrogen and thiophenolic sulfur. The complexes formed are non-electrolytes with the general formulae [ML(NO3)(2)H2O] and [M(HL)(2)(NO3)(2)]. The thermal decomposition of the complexes follows first order kinetics and the thermodynamic parameters of the decomposition are reported.

  DOI：

  10.1080/00945719909349517