2-[bis(2-trimethylsilylazanidylethyl)amino]ethyl-[diphenylboranylmethyl(dimethyl)silyl]azanide;oxolane;uranium(4+) | 1177023-28-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-[bis(2-trimethylsilylazanidylethyl)amino]ethyl-[diphenylboranylmethyl(dimethyl)silyl]azanide;oxolane;uranium(4+)
• CAS: 1177023-28-7
• 化学式: C₃₁H₅₅BN₄OSi₃U
• 分子量: 832.9
• InChiKey: WDUDXQJUMRWYEW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.67
• 重原子数：
  41
• 可旋转键数：
  5
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.58
• 拓扑面积：
  15.5
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  2-[bis[2-[methanidyl(dimethyl)silyl]azanidylethyl]amino]ethyl-trimethylsilylazanide;2-[bis(2-trimethylsilylazanidylethyl)amino]ethyl-trimethylsilylazanide;uranium(4+) 、 triethylammonium tetraphenylborate 以52%的产率得到2-[bis(2-trimethylsilylazanidylethyl)amino]ethyl-[diphenylboranylmethyl(dimethyl)silyl]azanide;oxolane;uranium(4+)
  参考文献：
  名称：

  A Crystallizable Dinuclear Tuck-In-Tuck-Over Tuck-Over Dialkyl Tren Uranium Complex and Double Dearylation of BPh₄⁻ To Give the BPh₂-Functionalized Metallocycle [U{N(CH₂CH₂NSiMe₃)₂(CH₂CH₂NSiMe₂CHBPh₂)}(THF)]

  摘要：

  The unprecedented formation of a dinuclear tuck-in-tuck-over tuck-over dialkyl Trenuranium(IV) complex and the first example of double dearylation of BPh4- in a molecular context to give a BPh2-functionalized uranium metallocycle are reported.

  DOI：

  10.1021/ja904459q