| 134815-81-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• CAS: 134815-81-9
• 化学式: C₂₈H₄₀O₁₀*C₄₈H₄₀N₄*4F₆P
• 分子量: 1789.35
• InChiKey: ZNAFRXZNSHUWKD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  14.41
• 重原子数：
  97.0
• 可旋转键数：
  0.0
• 环数：
  15.0
• sp3杂化的碳原子比例：
  0.26
• 拓扑面积：
  107.82
• 氢给体数：
  0.0
• 氢受体数：
  10.0

反应信息

• 作为反应物：
  描述：

  在 重水 作用下， 以 二氯甲烷 为溶剂， 生成
  参考文献：
  名称：

  一种新型的分子内1,2-芳烃-烯烃光环加成反应

  摘要：

  2-烯基-7-羟基-4-苯并二氢吡喃酮的新型分子内1,2-芳烃-烯烃光环加成反应（1）及其烷基醚（2和3）变为（4α，7α，9α）4,8,8-三甲基-14-氧杂四环（6.5.1 4,13 0.0 1,9-）十四碳-12-烯-2,11-二酮（4）进行说明。

  DOI：

  10.1016/0040-4039(93)88043-i
• 作为产物：
  描述：

  双(1,4-亚苯基)-34-冠10-醚 、 cyclobis(paraquat-4,4’-biphenylene) hexafluorophosphate 在 四丁基碘化铵 作用下， 以 氘代乙腈 为溶剂， 反应 72.0h， 以84%的产率得到
  参考文献：
  名称：

  Iodide-catalysed self-assembly of donor–acceptor [3]catenanes

  摘要：

  通过热力学控制的动态亲核取代反应，制备了高产的含Β-受体环双（对四氯苯-4,4²-联苯）和Β-供体芳香冠醚大环的带电供体-受体[3]链。

  DOI：

  10.1039/b716245f

文献信息

• Molecular Meccano. 2. Self-Assembly of [n]Catenanes
  作者：David B. Amabilino、Peter R. Ashton、Christopher L. Brown、Emilio Cordova、Luis A. Godinez、Timothy T. Goodnow、Angel E. Kaifer、Simon P. Newton、Marek Pietraszkiewicz

  DOI：10.1021/ja00109a011

  日期：1995.2

  The mutual molecular recognition between different: structural components in large rings has led to the template-directed synthesis of a wide range of catenanes composed of from two to five interlocked rings, The molecular self-assembly processes rely upon the recognition between (i) pi-electron rich and pi-electron deficient aromatic units and (ii) hydrogen bond donors and accepters, in the different components. In order to increase Our knowledge of the factors involved in such molecular self-assembly processes, a homologous series of [2]catenanes has been constructed using macrocyclic polyethers of the bis(p-phenylene)-(3n+4)-crown-n (n = 9-14) type as templates for the formation of the tetracationic cyclophane, cyclobis(paraquat-p-phenylene). Increasing the size of the tetracationic cyclophane to cyclobis(paraquat-4,4'-bitolyl) allows the simultaneous entrapment of two hydroquinone ring-containing macrocyclic polyethers affording a series of [3]catenanes, and one [4]catenane incorporating a cyclic dimer of the expanded cyclophane and three bis(p-phenylene)-34-crown-10 components. By analogy; increasing the number of hydroquinone rings in the macrocyclic polyether permits the self-assembly of more than one tetracationic cyclophane around the templates present in the macrocyclic polyether. In this context, the template-directed synthesis of two [3]catenanes, incorporating two cyclobis(paraquat-p-phenylene) components and either (i) tris(p-phenylene)51-crown-15 or (ii) tetrakis (p-phenylene)-68-crown-20, has been achieved and is reported. A combination of these two approaches has led to the successful self-assembly, in two steps, of a linear [4]catenane, together with a small amount of a [5]catenane: The creation of these intricate molecular compounds lends support to the contention that self-assembly is a viable paradigm for the construction of nanometer-scale molecular architectures incorporating a selection of simple components.
• Ashton, Peter R.; Brown, Christopher L.; Chrystal, Ewan J. T., Angewandte Chemie, 1991, vol. 103, # 8, p. 1055 - 1058
  作者：Ashton, Peter R.、Brown, Christopher L.、Chrystal, Ewan J. T.、Goodnow, Timothy T.、Kaifer, Angel E.、et al.

  DOI：——

  日期：——