aquo-bis(pyridine) bis([(4-methylphenyl)sulfonyl]-2-pyridyl-amide)cadmium(II) | 252555-70-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: aquo-bis(pyridine) bis([(4-methylphenyl)sulfonyl]-2-pyridyl-amide)cadmium(II)
• CAS: 252555-70-7
• 化学式: C₃₄H₃₄CdN₆O₅S₂
• 分子量: 783.223
• InChiKey: DQDAGDJDBQKUSQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  吡啶 、 N-(2-pyridyl)-p-toluenesulfonamide 、 镉 以 二氯甲烷 、 乙腈 为溶剂， 生成 aquo-bis(pyridine) bis([(4-methylphenyl)sulfonyl]-2-pyridyl-amide)cadmium(II)
  参考文献：
  名称：

  Cadmium(II) complexes with [(4-methylphenyl)sulfonyl]-2-pyridyl-amine: crystal structures of bis{[(4-methylphenyl)sulfonyl]-2-pyridyl-amide}cadmium(II); aquo-bis(pyridine) bis{[(4-methylphenyl)sulfonyl]-2-pyridyl-amide}cadmium(II) and 1,10-phenanthroline bis{[(4-methylphenyl)sulfonyl]-2-pyridyl-amide}cadmium(II)

  摘要：

  Electrochemical oxidation of cadmium in a solution of [(4-methylphenyl)sulfonyl]-2-pyridyl-amine (HL) in acetonitrile/ dichloromethane afforded the compound [CdL2]. When pyridine (py), 2,2'-bipyridine (bipy) or 1,10-phenanthroline (phen) was added to the electrolytic phase, [CdL(2)py(2)(H2O)], [CdL(2)bipy] and [CdL(2)phen] were obtained. The crystal structures of [CdL2] (1), [CdL(2)py(2)(H2O)] (2) and [CdL(2)phen] (3) have been determined by X-ray diffraction techniques. The complex [CdL2] is best described in terms of a linear polymer with the metal atom in a [CdN4O2] distorted octahedral environment. The [CdL(2)py(2)(H2O)] and [CdL(2)phen] complexes are monomeric, with the cadmium atoms in [CdN6O] distorted pentagonal bipyramid and [CdN6] trigonal prismatic environments, respectively. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(99)00265-0