9-(tribromogermyl)fluorene | 194018-37-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 芴
• 英文名称: 9-(tribromogermyl)fluorene
• 英文别名: 9-tribromogermylfluorene；Tribromo(9H-fluoren-9-YL)germane
• CAS: 194018-37-6
• 化学式: C₁₃H₉Br₃Ge
• 分子量: 477.516
• InChiKey: UVDCKGXWBNTFAE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.46
• 重原子数：
  17
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  9-(tribromogermyl)fluorene 、 tris(2-triethylstannoxyethyl)amine 以 氯仿 为溶剂， 以89%的产率得到1-(9-fluorenyl)germatrane
  参考文献：
  名称：

  Synthesis, characterization, and structures of 1-(9-Fluorenyl)-germatrane and 1-(Phenylacetylenyl)germatrane

  摘要：

  AbstractSyntheses of the title compounds, viz. N(CH2CH2O)3GeY (2 YFluorenyl; 4 YPhCC) by the reaction of X3GeY (1 YFluorenyl, XBr; 5 YPhCC, XCl) with N(CH2CH2OSnR3)3 (3 REt; 6 RBu) are reported including the preparation of the new compound 1. Identity and structures were established by elemental analyses, 1H and 13C NMR spectroscopy. 2 and 4 were characterized by mass spectrometry. Single crystal structures of 1, 2 and 4 were determined by X‐ray diffraction methods.

  DOI：

  10.1002/zaac.19976230723
• 作为产物：
  描述：

  dibromogermane dioxane 、 9-溴芴 以 1,4-二氧六环 为溶剂， 以83%的产率得到9-(tribromogermyl)fluorene
  参考文献：
  名称：

  Synthesis, characterization, and structures of 1-(9-Fluorenyl)-germatrane and 1-(Phenylacetylenyl)germatrane

  摘要：

  AbstractSyntheses of the title compounds, viz. N(CH2CH2O)3GeY (2 YFluorenyl; 4 YPhCC) by the reaction of X3GeY (1 YFluorenyl, XBr; 5 YPhCC, XCl) with N(CH2CH2OSnR3)3 (3 REt; 6 RBu) are reported including the preparation of the new compound 1. Identity and structures were established by elemental analyses, 1H and 13C NMR spectroscopy. 2 and 4 were characterized by mass spectrometry. Single crystal structures of 1, 2 and 4 were determined by X‐ray diffraction methods.

  DOI：

  10.1002/zaac.19976230723

文献信息

• Synthesis and Characterisation of 1-[9-(H, Me3Si, Me3Ge, Me3Sn)9-Fluorenyl]-3,7,10-trimethylgermatranes. The Crystal Structure Analysis of 1-(9-Fluorenyl)-3,7,10-trimethylgermatrane
  作者：Galina S. Zaitseva、Sergei S. Karlov、Gleb V. Pen'kovoy、Andrei V. Churakov、Judith A. K. Howard、Bettina A. Siggelkow、Evgueni V. Avtomonov、Jörg Lorberth

  DOI：10.1002/(sici)1521-3749(199904)625:4<655::aid-zaac655>3.0.co;2-n

  日期：1999.4

  The title compounds, viz. C13H8(R)Ge . (OCHMeCH2)(3)N (1: R = H, 2: R = Me3Si; 3: R = Me3Ge) were prepared as mixtures of diastereomers by the reaction of N(CH(2)CHMeOSnAlk(3))(3) (7: Alk = Et; 8: Alk = Bu) with C13H8(R)GeBr3 (4: R=H, 5: R=Me3Si; 6: R=Me3Ge), respectively. The synthesis of C13H8(Me3Sn)Ge (OCHMeCH2)(3)N (13) by the reaction of germatrane (1) with Me3SnNMe2 is reported. Identity and structures were established by elemental analyses,H-1 and C-13 NMR spectroscopy and mass spectrometry. The crystal structure of 1 was determined by X-ray diffraction methods.
• Churakov; Kuz'mina; Shutov, Russian Journal of Inorganic Chemistry, 2002, vol. 47, # 7, p. 983 - 986
  作者：Churakov、Kuz'mina、Shutov、Karlov、Selina、Zaitseva

  DOI：——

  日期：——
• Synthesis, characterization, and structures of 1-(9-Fluorenyl)-germatrane and 1-(Phenylacetylenyl)germatrane
  作者：Galina S. Zaitseva、Sergei S. Karlov、Andrei V. Churakov、Judith A. K. Howard、Evgeni V. Avtomonov、J�Rg Lorberth

  DOI：10.1002/zaac.19976230723

  日期：1997.7

  AbstractSyntheses of the title compounds, viz. N(CH2CH2O)3GeY (2 YFluorenyl; 4 YPhCC) by the reaction of X3GeY (1 YFluorenyl, XBr; 5 YPhCC, XCl) with N(CH2CH2OSnR3)3 (3 REt; 6 RBu) are reported including the preparation of the new compound 1. Identity and structures were established by elemental analyses, 1H and 13C NMR spectroscopy. 2 and 4 were characterized by mass spectrometry. Single crystal structures of 1, 2 and 4 were determined by X‐ray diffraction methods.