Cu2(benzoate)4(pyrazine) | 226890-66-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Cu2(benzoate)4(pyrazine)
• CAS: 226890-66-0
• 化学式: C₃₂H₂₄Cu₂N₂O₈
• 分子量: 691.643
• InChiKey: USVNOSKVRCGNQI-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  Cu2(benzoate)4(pyrazine) 、 二氧化碳 以 neat (no solvent) 为溶剂， 以0%的产率得到Cu2(benzoate)4(pyrazine)*3(carbon dioxide)
  参考文献：
  名称：

  Structural determination of copper(II) benzoate–pyrazine containing carbon dioxide molecules

  摘要：

  A novel gas inclusion solid was generated by cooling an empty host crystal of copper(II) benzoate-pyrazine in a carbon dioxide environment and characterized by single-crystal X-ray diffraction analysis. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2003.09.011

文献信息

• Selective Generation of Organic Aggregates Included within Metal−Organic Micropores through Vapor Adsorption
  作者：Satoshi Takamizawa、Teruo Saito、Takamasa Akatsuka、Ei-ichi Nakata

  DOI：10.1021/ic048351s

  日期：2005.3.1

  The ethanol vapor adsorption behavior and the inclusion crystal structure of a 1 D-transformable coordination polymer host were characterized. The adsorption jump was observed during phase transition or two-phase equilibrium with abnormal adsorption enthalpy caused by the nature of "mass induced phase transition." The included ethanol guests selectively form O-H...O hydrogen bonded pairs inside channels, suggesting selective construction of a specific cluster/aggregate in pores under control of thermodynamic factors and cooperative intermolecular interactions among the guest and channel surface.