n-butyltris(2-pyrimidinethiolato-N,S)tin(IV) | 156271-26-0

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: n-butyltris(2-pyrimidinethiolato-N,S)tin(IV)
• 英文别名: butyl-tris(pyrimidin-2-ylsulfanyl)stannane
• CAS: 156271-26-0
• 化学式: C₁₆H₁₈N₆S₃Sn
• 分子量: 509.267
• InChiKey: FWHYVOMBLFQSPL-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  丁基三氯化锡 、 2-巯基嘧啶 在 NaOCH₃ 作用下， 以 甲醇 、 氯仿 为溶剂， 生成 n-butyltris(2-pyrimidinethiolato-N,S)tin(IV)
  参考文献：
  名称：

  n-Butyltris(2-pyrimidinethiolato-N,S)tin(IV)

  摘要：

  The crystal structure of the title compound contains two crystallographically independent molecules. The 2-pyrimidinethiolato ligands (SPym) are bidentate. Sn-S bond distances range from 2.445 (4) to 2.561 (5) angstrom and Sn...N coordination is inferred from short Sn-N distances [2.470 (5)-2.622 (6) angstrom]. The coordination polyhedron around Sn in both molecules can be considered as a distorted pentagonal bipyramid. The pentagonal plane in each molecule is formed by two SPym ligands, with S atoms in cis positions, and the N atom of the third SPym ligand. The S atom of this ligand, which is arranged nearly perpendicular to the equatorial plane, and the C(n-butyl) atom occupy the axial positions. Intermolecular distances shorter than the sum of the van der Waals radii were not found.

  DOI：

  10.1107/s0108270193008315