[2-[4-[2-di(propan-2-yl)phosphanylphenyl]phenyl]phenyl]-di(propan-2-yl)phosphane;nickel | 1226977-45-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [2-[4-[2-di(propan-2-yl)phosphanylphenyl]phenyl]phenyl]-di(propan-2-yl)phosphane;nickel
• CAS: 1226977-45-2
• 化学式: C₃₀H₄₀NiP₂
• 分子量: 521.285
• InChiKey: XSUVIPJDFFHICT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.87
• 重原子数：
  33
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  [2-[4-[2-di(propan-2-yl)phosphanylphenyl]phenyl]phenyl]-di(propan-2-yl)phosphane;nickel 以 四氢呋喃 、 甲苯 、 乙腈 为溶剂， 生成
  参考文献：
  名称：

  Nickel Hydrides Supported by a Non-Innocent Diphosphine Arene Pincer: Mechanistic Studies of Nickel−Arene H-Migration and Partial Arene Hydrogenation

  摘要：

  Nickel hydrides supported by a terphenyl diphosphine were synthesized and found to undergo nickel-to-arene H-transfers. Some of the resulting complexes also undergo the reverse (C-to-Ni) H-migration, indicating the potential for storing H-equivalents in this type of pincer ligand. NMR spectroscopy, single crystal X-ray diffraction, and isotopic labeling studies investigating the mechanism of these processes are discussed.

  DOI：

  10.1021/ja200368y
• 作为产物：
  描述：

  在 dimethylbenzylamine 作用下， 以 四氢呋喃 为溶剂， 生成 [2-[4-[2-di(propan-2-yl)phosphanylphenyl]phenyl]phenyl]-di(propan-2-yl)phosphane;nickel
  参考文献：
  名称：

  Nickel Hydrides Supported by a Non-Innocent Diphosphine Arene Pincer: Mechanistic Studies of Nickel−Arene H-Migration and Partial Arene Hydrogenation

  摘要：

  Nickel hydrides supported by a terphenyl diphosphine were synthesized and found to undergo nickel-to-arene H-transfers. Some of the resulting complexes also undergo the reverse (C-to-Ni) H-migration, indicating the potential for storing H-equivalents in this type of pincer ligand. NMR spectroscopy, single crystal X-ray diffraction, and isotopic labeling studies investigating the mechanism of these processes are discussed.

  DOI：

  10.1021/ja200368y

文献信息

• Synthesis and C−C Coupling Reactivity of a Dinuclear Ni^I−Ni^I Complex Supported by a Terphenyl Diphosphine
  作者：Alexandra Velian、Sibo Lin、Alexander J. M. Miller、Michael W. Day、Theodor Agapie

  DOI：10.1021/ja101699a

  日期：2010.5.12

  Mono- and bimetallic complexes of nickel supported by a terphenyl diphosphine have been synthesized. The reported complexes show diverse metal-arene interactions in the solid state. Reactions of an o,o'-biphenyldiyl dinickel complex with CO and dichloroalkanes lead to fluorene derivatives, indicating the formation of carbon-carbon bonds at a bimetallic moiety.